supported financially by the Singapore Ministry of Education(MOE)Academic Research Fund(AcRF)Tier 2 grant(MOE-T2EP10222-0003);the Agency for Science,Technology and Research Manufacturing,Trade,and Connectivity(A*STAR MTC)project,Singapore(M22K2c0083).
The aromaticity and electronic properties of monocyclic or polycyclicπ-conjugated molecules have been widely studied.However,the related research on fullyπ-conjugated multicyclic macrocycles(MMCs)remains limited mai...
the support from the Ministry of Education;Singapore (MOE,No.MOET2EP10120-0007);A^(*)STAR under its Advanced Manufacturing and Engineering Program (No.A2083c0051);the SUTD Kickstarter Initiative (No.SKI 2021_01_01);supported by QMUL Research-IT for computational resources,and the ARCHER UK National Supercomputing Service (No.EP/X035859/1) via the Materials Chemistry Consortium;the Molecular Modelling Hub for computational resources,MMM Hub,which is partially funded by EPSRC (No.EP/T022213/1);Leverhulme Trust (No.RPG-2019-122) for funding
Cyclooctatetraene(COT)attachment to fluorophores(“self-healing”dyes)is known for quenching reac-tive triplet states via triplet-state energy transfer(TET),enhancing photostability.However,COT’s impact on singlet st...
The reaction of NdCl_3 with lithium methylnaphthalene in 1:2 mole ratio in THF generates black powder. The powder reacts with cyclooctatetraene(COT)in THF to form the title complex.[Li(THF)_4Nd(C_8H_8)_2]· 2THF cryst...