ANTIAROMATICITY

作品数：5被引量：3H指数：1
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相关领域：理学更多>>
相关期刊：《Fundamental Research》《Organic Chemistry Frontiers》《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》更多>>
相关基金：国家自然科学基金更多>>
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Synthesis,Structure and Chemical Bonding of Polyantimony Clusters Containing Coinage Metals[M_(2)Sb_(14)]^(4-)(M=Cu,Ag)
《Chinese Journal of Chemistry》2024年第6期617-622,共6页Wei-Xing Chen Yu-He Xu Cui-Cui Wang Lei Qiao Zi-Yan Guo Wen-Juan Tian Zhong-Ming Sun 
supported by the National Natural Science Foundation of China(Nos.92161102,22371140 to Z.-M.Sun and 22301143 to L.Qiao);the Fundamental Research Program of Shanxi Province(202103021224028 and 202204021301010 to W.-J.Tian);the Natural Science Foundation of Tianjin City(21JCZXJC00140 to Z.-M.Sun).
Binary polyantimony clusters,namely[Cu_(2)Sb_(14)]^(4–) and [Ag_(2)Sb_(14)]^(4–),containing coinage metals,were successfully synthesized and characterized,in which two homoatomic Sb73–subunits are bridged by two co...
关键词：Polyantimony cluster Copper SILVER ANTIAROMATICITY Metallophilic interaction Quantum chemical calculations 
The application of aromaticity and antiaromaticity to reaction mechanisms被引量：1
《Fundamental Research》2023年第6期926-938,共13页Qin Zhu Shuwen Chen Dandan Chen Lu Lin Kui Xiao Liang Zhao Miquel Solà Jun Zhu 
the National Natural Science Foundation of China(22073079,22025105 and 21873079);the Ministry of Education of China(H20200504);the Top-Notch Young Talents Program of China is gratefully acknowledged;M.S.thanks the Ministerio de Ciencia e Innovación of Spain(project PID2020-113711GB-I00);the Generalitat de Catalunya(project 2017SGR39).
Aromaticity,in general,can promote a given reaction by stabilizing a transition state or a product via a mobility ofπelectrons in a cyclic structure.Similarly,such a promotion could be also achieved by destabilizing ...
关键词：AROMATICITY ANTIAROMATICITY Reaction mechanism Frustrated Lewis pairs Dinitrogen activation Small molecule activation 
Progress of Indeno-type Organic Diradicaloids被引量：1
《Chemical Research in Chinese Universities》2023年第2期161-169,共9页GUO Jiaxiang TIAN Xinyu WANG Yue DOU Chuandong 
National Natural Science Foundation of China(No.22175074);Jilin Scientific and Technological Development Program,China(No.20220101054JC).
Organic diradicaloids have unusual open-shell nature and properties and are promising materials for organic electronics,spintronics,energy storage and nonlinear optics.In this review,we focus on indeno-type organic di...
关键词：Polycyclic hydrocarbon Open shell Quinoidal conjugation Diradical character ANTIAROMATICITY 
Antiaromaticity-promoted radical anion stability in α-vinyl heterocyclics
《Organic Chemistry Frontiers》2022年第5期1427-1436,共10页Lu Lin Jun Zhu 
This project was supported by the National Science Foundation of China(22073079 and 21103142);the Top-Notch Young Talents Program of China.
As an electron-rich species,radical anions have a wide range of applications in organic synthesis.In addition,aromaticity is an essential concept in chemistry that has attracted considerable attention from experimenta...
关键词：synthesis RADICAL HETEROCYCLIC 
Recent Advances in Aromatic Antimony Clusters被引量：1
《Chinese Journal of Chemistry》2018年第10期955-960,共6页Lei-Jiao Li Basharat Ali Zhongfang Chen Zhong-Ming Sun 
This work was supported in China by National Natural Science Foundation of China （Nos. 21722106 and 21571171）, CAS-TWAS President Fellowship, and Youth Foundation project of Jilin prov- ince 20180520009JH, and in USA by NSF-CREST Center for Innova- tion, Research and Education in Environmental Nanotechnology （CIRE2N） （Grant Number HRD-1736093）.
This paper highlights the compounds containing Sb cluster fragments, either synthesized in the solid-state, discovered from the gas phase, or only theoretically predicted. These Sbn clusters feature unique chemical bo...
关键词：AROMATICITY ANTIAROMATICITY Sb clusters chemical bonding 
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