CYCLEN

作品数:17被引量:8H指数:1
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相关作者:余孝其张骥孙小强杨帆李坤更多>>
相关机构:四川大学南京大学江苏工业学院渭南师范学院更多>>
相关期刊:《Science China Chemistry》《有机化学》《Chinese Journal of Structural Chemistry》《渭南师范学院学报》更多>>
相关基金:国家自然科学基金国家教育部博士点基金陕西省教育厅科研计划项目国家重点基础研究发展计划更多>>
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A phenylphenthiazide anchored Tb(Ⅲ)-cyclen complex for fluorescent turn-on sensing of ClO^(-)
《Chinese Chemical Letters》2025年第2期269-273,共5页Ya-Ping Liu Zhi-Rong Gui Zhen-Wen Zhang Sai-Kang Wang Wei Lang Yanzhu Liu Qian-Yong Cao 
supported by the National Nature Science Foundation of China(Nos.22061028 and 22361028);Jiangxi Provincial Natural Science Foundation(No.20224ACB203012)。
A phenylphenothiazine anchored Tb(Ⅲ)-cyclen complex PTP-Cy-Tb for hypochlorite ion(ClO^(-))detection has been designed and prepared.PTP-Cy-Tb shows a weak Tb-based emission with AIE-characteristics in aqueous solutio...
关键词:Phenylphenothiazine Tb(III)complex AIE Hypochlorite ion SENSING 
Self-assembled bright luminescent hierarchical materials from a tripodal benzoate antenna and heptadentate Eu(III) and Tb(III) cyclen complexes
《Frontiers of Chemical Science and Engineering》2019年第1期171-184,共14页Aramballi J.Savyasachi David F.Caffrey Kevin Byrne Gerard Tobin Bruno D'Agostino Wolfgang Schmitt Thorfinnur Gunnlaugsson 
Science Foundation Ireland (PI awards 13/IA/1865 to T.G. and 13/IA/1896 to W.S.);the Irish Research Council (Postgraduate Scholarship to DC);the European Research Council (CoG 2014 - 647719 to W.S.);the School of Chemistry, Trinity College Dublin.
The europium heptadentate coordinatively unsaturated (Eu(III)) and the terbium (Tb(III)) 1,4,7,10-tetraazacyclododecane (cyclen) complexes 1 and 2 were used in conjunction with ligand 3 (1,3,5-benzene-trisethynylbenzo...
关键词:self-assembly supramolecular chemistry lanthanides EU(III) and TB(III) COMPLEXES luminescence metallostars 
Synthesis and Crystal Structure of the Hydrogen Bromide Salt of 1,4,7,10-Tetrakis(2-((4-methoxy)phenoxy) ethyl)-1,4,7,10-tetraazacyclododecane
《Journal of Materials Science and Chemical Engineering》2017年第10期1-11,共11页Wei Zhao Yun Wang Aijian Wang 
A novel molecule tetra-N-alkylation of cyclen (1,4,7,10-tetraazacyclododecane), 1,4,7,10-tetrakis(2-((4-methoxy)phenoxy)ethyl)-1,4,7,10-tetraazacyclododecane 1, was synthesized and structurally characterized by the si...
关键词:Synthesis Crystal Structure CYCLEN DERIVATIVE 
A 3D Hydrogen-bonded 2-Fold Interpenetrated Supramolecular Structure of Cyclen Derivative
《Chinese Journal of Structural Chemistry》2017年第1期53-58,共6页孙小强 徐达 李正义 张秀芹 
Supported by the National Natural Science Foundation of China(Nos.21572026 and 21002009);the Scientific and Technological Project of Changzhou(CE20135009);Changzhou University,Advanced Catalysis and Green Manufacturing Collaborative Innovation Center
The title compound 1,4,7,10-tetrakis(2-(4-methoxyphenoxy)ethyl)-1,4,7,10-tetraazacyclododecane hydrobromide derivated from cyclen has been synthesized by 4-methoxyphenol via two steps and characterized by ^1H NMR ...
关键词:cyclen derivative synthesis crystal structure H-bonding interpenetration 
[Co(cyclen)(ala)]^(2+)与[Co(cyclen)(pn)]^(3+)配合物电子圆二色谱的理论分析
《山西大学学报(自然科学版)》2016年第4期644-649,共6页赵霞 贾杰 
使用密度泛函理论(DFT)在B3LYP/6-311++G(2d,p)水平上优化了两种钴配合物[Co(cyclen)(ala)]2+与[Co(cyclen)(pn)]3+(Cyclen=1,4,7,10-四氮环十二烷胺,ala=(S)-丙氨酸,pn=(R)-1,2丙二胺)在水溶液中的几何构型,在此基础上,又用含时密度泛...
关键词:DFT ECD谱 Co配合物 
Cyclen全同取代衍生物碱金属配体的合成
《江苏大学学报(自然科学版)》2016年第1期121-124,共4页王爱健 赵炜 孙小强 
江苏省高校自然科学基金资助面上项目(15KJB430007);江苏大学高级人才启动基金资助项目(13JDG066)
设计合成了含有苯环基团支链的1,4,7,10-四氮杂环十二烷(Cyclen)全同取代衍生物1,4,7,10-四(2-对甲氧基苯氧基)乙基-1,4,7,10-四氮杂环十二烷2.化合物2的分子中含有一个Cyclen底座和4条醚链侧臂,前者易与金属离子配位,后者可通过弱相互...
关键词:CYCLEN 衍生物 碱金属 核磁 荧光 
Tetraphenylethene based zinc complexes as fluorescent chemosensors for pyrophosphate sensing
《Chinese Chemical Letters》2015年第7期877-880,共4页Hao-Ran Xu Kun Li Shu-Yan Jiao Ling-Ling Li Sheng-Lin Pan Xiao-Qi Yu 
financially supported by the National Program on Key Basic Research Project of China (973 Program, Nos. 2012CB720603, 2013CB328900);the National Science Foundation of China (Nos. 21232005, 21321061, J1310008and J1103315);the Specialized Research Fund for the Doctoral Program of Higher Education in China (No. 20120181130006)
We described a serious of zinc complexes that exhibit characteristic fluorescence responses toward pyrophosphate (PPi) and adenosine triphosphate (ATP) in aqueous media. These novel probes exploited tetraphenyleth...
关键词:Tetraphenylethene Cyclen PyrophosphatesZinc complex 
新型配合物[Cu(cyclen)(H_2O)]^(2+)的密度泛函理论研究被引量:1
《渭南师范学院学报》2011年第6期59-62,共4页朱海燕 李珺 任颜卫 姚焕英 
陕西省教育厅专项基金资助项目(2010JK548);渭南师范学院科研计划项目(07YKZ004)
[Cu(cyc len)(H2O)]2+(cyc len=1,4,7,10-四氮杂环十二烷)是一种新型的大环配合物.在其实验所测晶体结构基础上,文章运用量子化学密度泛函理论中的B3LYP/6-31G(d)方法,对其结构参数进行优化和频率分析,结果表明优化结构为稳定结构,且与...
关键词:1 4 7 10-四氮杂环十二烷 铜配合物 密度泛函理论 量子化学计算 
Synthesis and Crystal Structure of 1,4,7,10-Tetrakis-(2-(2,3-difluorophenyl)-ethyl)-1,4,7,10-tetraazacyclododecane
《Chinese Journal of Structural Chemistry》2011年第1期7-11,共5页孙小强 崔源 张秀芹 陈强 席海涛 
supported by the National Natural Science Foundation of China (20872051)
The new compound 1,4,7,10-tetrakis-(2-(2,3-difluorophenyl) ethyl) -1,4,7,10-tetra-zacyclododecane 2 has been synthesized and structurally characterized by single-crystal X-ray diffraction. The molecule turned into...
关键词:synthesis crystal structure CYCLEN tetra-N-alkylation 
Synthesis,DNA binding and cleavage studies of the copper(Ⅱ) complexes of PNA-cyclen conjugates
《Science China Chemistry》2011年第1期129-136,共8页ZHANG Yu HUANG Yu ZHANG Ji ZHANG DaWei LIU JunLiang LIU Qiang LIN HongHui YU XiaoQi 
financially supported by the National Natural Science Foundation of China (20725206, 20732004 & 20902062);Program for Changjiang Scholars and Innovative Research Team in University, the Key Project of Chinese Ministry of Education in China and Scientific Fund of Sichuan Province for Outstanding Young Scientists
Two dinucleotide PNA-cyclen copper(II) complexes with α-PNA (P1) and classical PNA (P2) backbones were synthesized and characterized.The interactions between title complexes and DNA were investigated under physiologi...
关键词:PNA CYCLEN copper complexes DNA binding DNA cleavage 
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