METALATION

作品数：6被引量：5H指数：2
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相关领域：理学更多>>
相关作者：华星陈永婷陈胜利更多>>
相关机构：武汉大学曲阜师范大学更多>>
相关期刊：《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Chemical Physics》《Chinese Journal of Catalysis》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金福建省自然科学基金更多>>
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Photocatalytic reduction of CO_(2) with H_(2)O into C_(2)H_(6) mediated by dual metalation strategy
《Science China Chemistry》2024年第5期1381-1383,共3页Mei Wang Tong-Bu Lu 
Artificial solar-energy-driven CO_(2) reduction into value-added fuels under mild conditions provides a promising strategy to mitigate energy crisis and alleviate environmental issues around the world. Among diverse p...
关键词：reduction desirable VALUE 
Post-synthetic metalation of organic cage for enhanced porosity and catalytic performance被引量：2
《Science China Chemistry》2023年第6期1763-1770,共8页Miao Yang Xun Chen Yifei Xie El-Sayed MEl-Sayed Ning Xu Wenjing Wang Kongzhao Su Daqiang Yuan 
supported by the National Natural Science Foundation of China(22071244);the Youth Innovation Promotion Association CAS(2022305);the Natural Science Foundation of Fujian Province of China(2022J01503,2020J05087);the China Postdoctoral Science Foundation(2020M671954)。
Porous organic cages(POCs)have shown great potential in many applications,and post-synthetic modification(PSM)has been confirmed to be an effective strategy to tailor their structures and related functionalities.Howev...
关键词：porous organic cage(POC) resorcinarene post-synthetic metalation(PSM) gas adsorption and separation CO_(2)cycloaddition 
Chelating Metal Ions in a Metal-Organic Framework for Constructing a Biomimetic Catalyst Through Post-modification
《Chemical Research in Chinese Universities》2022年第6期1542-1546,共5页PANG Kuan XUE Huan LIU Haixiong SUN Jing LIU Tianfu 
supported by the National Key Research and Development Program of China (No.2018YFA0704502);the National Natural Science Foundation of China (No.22033008);the Foundation of Director of Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China (Nos.2021ZZ103,2021ZR105).
Crystal engineering,as a burgeoning technology,has been widely used to construct metalloporphyrins biomimetic catalysts.Herein,a bimetallic metal-organic framework(MOF)was constructed by 4-(4-carboxyphenyl)-1,2,4-tria...
关键词：Metal-organic framework(MOF) Bimetallic MOF Crystal structure METALATION 
Controlling Metalation Reaction of Phthalocyanine with Cobalt at Single-Molecule Level on Au(111)Surfac
《Chinese Journal of Chemical Physics》2021年第4期419-428,I0002,共11页Liang Zhu Bin Li Lei Dong Wei Feng Ai-di Zhao Bing Wang 
This work is supported by the Ministry of Sci-ence and Technology of China(No.2016YFA0200603,No.2017YFA0204904);the Strategic Priority Re-search Program of Chinese Academy of Sciences(XDB36000000);the National Natural Science Foun-dation of China(No.21972129);Anhui Initiative in Quantum Information Technologies(AHY090000).
Metalation reac-tion of metal-free phthalocyanine molecule with Co atom adsorbed on Au(111)surface has been studied in situ at single atom/molecule scale by low-temperature scanning tunneling microscopy(STM)experiment...
关键词：PHTHALOCYANINE Metalation reaction Scanning tunneling microscopy 
Theoretical study of stability of metal-N_4 macrocyclic compounds in acidic media被引量：1
《Chinese Journal of Catalysis》2016年第7期1166-1171,共6页陈永婷 华星 陈胜利 
supported by the National Basic Research Program of China(973 program,2012CB215500 and 2012CB932800)~~
Fe and Co porphyrins and phthalocyanines are excellent catalysts for the oxygen reduction reaction （ORR） and are promising alternatives to Pt in fuel cells. However, the stability of these molecular catalysts in aci...
关键词：MetalloporphyrinMetallophthalocyanineDe-metalationMetal ion-proton exchangeDFT calculationSubstituent group 
Mechanistic study of copper-catalyzed intramolecular ortho-C-H activation/carbon-nitrogen and carbon-oxygen cyclizations被引量：2
《Science China Chemistry》2013年第5期619-632,共14页TANG ShiYa GONG TianJun FU Yao 
the financial support from the National Basic Research Program of China (973 program, 2012CB215306);the National Natural Science Foundation of China (NSFC, 20832004, 20972148);CAS(KJCX2-EW-J02)
Intramolecular ortho-C-H activation and C-N/C-O cyclizations of phenyl amidines and amides have recently been achieved under Cu catalysis. These reactions provide important examples of Cu-catalyzed functionalization o...
关键词：mechanism DFT copper C-H activation concerted metalation-deprotonation 
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