supported by the National Key R&D Program of China(No.2021YFB3700103).
The demand for anisotropic aerogels with excellent comprehensive properties in cutting-edge fields such as aerospace is growing.Based on the above background,a novel heterocyclic para-aramid nanofiber/reduced graphene...
by the National Key R&D Plan(No.2017YFC1104800);the National Natural Science Foundation of China(Nos.21901249 and 21950410529);Taishan Scholars Program of Shandong Province(No.tsqn201812112);“135”Projects Fund of CAS-QIBEBT Director Innovation Foundation and DICP&QIBEBT United Foundation(No.UN201701).
The isoselective ring-opening polymerization of racemic lactide was achieved by combining N-heterocyclic olefin(NHO)with mono(thio)ureas or bis(thio)ureas as catalytic systems.The polymerization process shows high ste...
supported by the National Natural Science Foundation of China(No.21634002);the Fundamental Research Funds for the Central Universities(Nos.XK1802-2 and XK1802-1).
Neodymium complexes containing N heterocyclic carbene(NHC)ligands,NdCl5[1,3,R(NCH=)2C]-THF,(Nd1:R=2,6-Pr2C6H3,x=0;Nd2:R=2,6-Et2C6H3,x=1;Nd3:R=2.4,6-Me3C6H2,x=1)were synthesized and employed as precatalysts for the coo...
This work reports synthesis and characterization of heterocyclic functionalized polymers, poly(triazole-etherimidazole)s(PTAEI), from a dialkyne-terminated compound, 3-(4,5-bis(4-(propargyloxy)phenyl)-1H-imid...
the National Natural Science Foundation of China(No.20774078);the Key Program of the National Natural Science Foundation of China(No.20434020);the Special Funds for Major Basic Research Projects(No.G 2005CB623802)
An aromatic heterocyclic Schiff base neodymium complex bearing thiazole was synthesized and its activity in the ring-opening polymerization ofε-caprolactone(CL)was examined.The conditions of the CL/Nd molar ratio,mon...
The synthesis and characterization of a series of novel comb-like polymethacrylates bearing heterocyclic azo group and mesogenic group are described. The thermal properties of the polymers such as thermal stability an...
The methacrylate monomers bearing mesogenic group and heterocyclicazo dye have been synthesized. The monomeric dye was copolymerized with the mesogenicmonomer using a free radical initiator to produce polymers useful ...
The polymerization kinetics of 4, 4'-biphenyldicarbonitrile and other substituted ben-zonitriles catalyzed by cobaltic acetylacetonate was studied. The structure of polymer ofdifferent substituted benzonitrile was als...
The bulk polymerization of benzonitrile catalyzed by Co(Ⅱ), Co(Ⅲ) and Fe(Ⅲ) acetylacetonate was studied. The results of kinetics study show that the rate of polymerization was proportional to first power of the con...
The polymerization rates of three cyanopyridines catalyzed by cuprous chloride-zinc system are measured, and the structure of the formed polymer is also determined. Compared with aromatic nitrile, cyanopyridines polym...