Supported by the National Natural Science Foundation of China(Nos.51772162,21571112,51572136 and 21601103);the Scientific and Technical Development Project of Qingdao,China(No.17-1-1-78-jch) and the Taishan Scholars Program,Shangdong Province,China.
Three salts constructed by 5-amino-2,4,6-triiodoisophthalic acid(ATIPA) with N-heterocycles aromatic coformers such as pyridine tetrazolium, tetramethylpyraziiie and cyanuric acid were synthesized by slowing evaporati...
Funded by the National Natural Science Foundation of China for Young Schoolar(No.51103016);the Natural Science Foundation of Jiangsu Province(No.BK2011241);the State Key Laboratory for Modification of Chemical Fibers and Polymer Materials(No.LK1001);the Changzhou University Projects(No.CZUYJ1009&CJ20125006)
Novel poly(thioether imide)s were synthesized by 2,5-dimercapto-l,3,4-thiadiazole, and aromatic heterocyclic chlorodiimids through nucleophilic!substitution reaction as alkali catalysts were presented. The poly(thi...
the National Natural Science Foundation of China(No.20774078);the Key Program of the National Natural Science Foundation of China(No.20434020);the Special Funds for Major Basic Research Projects(No.G 2005CB623802)
An aromatic heterocyclic Schiff base neodymium complex bearing thiazole was synthesized and its activity in the ring-opening polymerization ofε-caprolactone(CL)was examined.The conditions of the CL/Nd molar ratio,mon...
This work was supported by the National Natural Science Foundation of China (Grant No. 20072024).
Arylamines are very common and important organic molecules. Acting as important intermediates in medical and chemical industry, they are widely used in the synthesis of Pharmaceuticals, dyes, pesticides, rubber additi...
The reaction of Dimroth rarrangement for the synthesis of N6 substituted adenosine and adenine was discussed, and a series of N6-pyridylmethyl substituted adenosines and adenines were synthesized.
The bulk polymerization of benzonitrile catalyzed by Co(Ⅱ), Co(Ⅲ) and Fe(Ⅲ) acetylacetonate was studied. The results of kinetics study show that the rate of polymerization was proportional to first power of the con...
Project supported by the National Natural Science Foundation of China
One of the typical phenomena of intramolecular ligand-ligand interaction in complexes is the aromatic-ring stacking which depends on the stacking of those non-coordinating aromatic rings. Since 1974 H. Sigel reported ...
This paper described the ~3H NMR determination of the positions and content of 24 tritium labeled aromatic and heterocyclic compounds prepared by catalytic tritiation derivatives, pyrrole, 1,2,4-triazole, thiazole, be...
The polymerization rates of three cyanopyridines catalyzed by cuprous chloride-zinc system are measured, and the structure of the formed polymer is also determined. Compared with aromatic nitrile, cyanopyridines polym...
The polymerization kinetics of 4, 4′-biphenyldicarbonitrile using cuprous chloride-zinc system as catatyst was investigated. the concentration of unreacted cyano group was measured by infrared spectroscopic analysis ...