supported by the Foundation of Education Department of Henan Province(15A150037)
A new organic-inorganic hybrid sandwich-type polyoxotungstate [Cu(dien)-(H2O)2]2[{Cu(dien)(H2O)}3{Cu(4.5)W(0.5)(B-α-Sb W9O(33))2}](OH)4·7H2O(1, dien = diethylenetriamine) has been hydrothermally ...
Supported by theNNSFC(No.51108122);Open Project of State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(No.QA201025);Fundamental Research Funds for the Central Universities(No.HIT.NSRIF.2010053);Science and Technology Innovation Talents Special Foundation of Harbin(2010RFQXG035 and 2007RFXXG018)
A new sandwiched polyoxometalate [HK11Cd4Cl2(PW9034)2]·18H2O (1), incor- porating a unique hybrid tetranuclear cadmium cluster (abbreviated to {Cd4}) with two trivacant polyanions [B-α-PW9O34]9-, has been hydr...
Supported by the Natural Science Foundation of Fujina Province(No.2008I0013);the Foundation of Education Committee of Fujian Provinc(No.JB11002)
A new supramolecular compound (4,4'-bipyH)4[SiW12O40](4,4'-bipy) (4,4'-bipy = 4,4'-bipyridine) was synthesized hydrothermally and characterized by single-crystal X-ray diffraction and IR spectrum. The crysta...
Supported by the National Natural Science Foundation of China (No. 31060121)
The utilization of polyoxometalates (POMs) or their derivatives as homogeneous or heterogeneous catalysts in alkene epoxidation is a subject of considerable research activity[1]. The limitation to the use of POMs in...
supported by the National Natural Science Foundation of China;the Program for New Century Excellent Talent in Henan University;the Foundation of Education Department of Henan Province;the Natural Science Foundation of Henan Province
A novel 3D polyoxotungstate [Ca(H2O)2][Ca(H2O)3]H2[P2W18O62]·9H2O(1) has been synthesized by the conventional aqueous solution method and characterized by IR spectrum,elemental analyses,single-crystal X-ray dif...
supported by the Analysis and Testing Foundation of Northeast Normal University
A new heteropolyoxotungstate [(C2H4N2)4(P4Co3W4O28H6)(H2C2O4)]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1...
supported by the National Natural Science Fund for Distinguished Young Scholars of China (No 20725101);the 973 Program (No 2006CB932904);the NSF of Fujian Province (No E0510030);the NNSFC (No 20521101);the Research Foundation of Education Bureau of Fujian Province (No JA08053)
One new sandwich-type tetra-nickel substituted polyoxotungsate,[Ni(trien)]4-[Ni4(H2O)2(HPW9O34)2]·4H2O(1,trien=triethylenetetramine),has been hydrothermally synthesized and characterized by IR,elemental analy...
supported by the national natural science foundation of China (No 20771034);Henan Innovation Project for University Prominent Research Talents;the Natural Science Foundation of Henan Province (No 0524480020)
A new sandwich transition metal substituted polyoxotungstate, [NH3(CH2)4NH3]6[Co4(H2O)2(B-α-GeW9O34)2]}·7H2O 1, was hydrothermaUy synthesized and characterized by IR spectra and single-crystal X-ray diffractio...
This work was supported by the Natural Science Foundation of Fujian Province (No. E0420001) and NCETFJ.
An organic-inorganic compound [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O40(H2)]·4H2O (Mr = 4048.00) was prepared from the hydrothermal reaction of Na2WO4.2H2O, CuC12·2H20, 2,2'-bipyridine (2,2'-bpy) and H2O ...
The work was supported by NNSFC (No. 20501011);Liaocheng University (31801)
One new polyoxotungstate complex H6Na2K4(H2W12O42)Cl2·14H2O 1 has been prepared in the beaker solution and characterized by elemental analysis and IR spectroscopy. Crystal data: H36Cl2K4W12Na2O56, Mr = 3411.77, mo...