supported by the National Key R&D Program of China(2022YFA1505100,2021YFA1500100);the National Natural Science Foundation of China(22031008);the Fundamental Research Funds for the Central Universities(2042022rc0030,2042023kf0108,2042023kf1002);the Science Foundation of Wuhan(2020010601012192)。
Dihydropyran(DHP)compounds are not only found in natural products and bioactive molecules,but also serve as important precursors in organic synthesis.Nonetheless,traditional methods for the construction of such compou...
supported by the National Natural Science Foundation of China(21872155,21473224);Cooperation Foundation of Dalian National Laboratory for Clean Energy(DNL 180303);Key Research Project of Frontier Science of Chinese Academy of Sciences(QYZDJ-SSW-SLH051);the Youth Innovation Promotion Association,CAS(2016371);the Suzhou Science and Technology Development Plan(SYG201626)~~
A highly efficient and green process was developed for the synthesis of useful 5-amino-1-pentanol(5-AP)from biomass-derived dihydropyran by coupling the in situ generation of 5-hydroxypentanal(5-HP,via the ring-openin...
supported by grants from the Industrial Research Project of Science and Technology Department of Shaanxi Province(No.2013K09-25)
Two novel dihydropyran compounds (1 and 2) containing a triphenylamine group were synthesized and characterized. The structure of compound 2 was verified by single-crystal X-ray crystallography. It crystallizes in t...
Diammonium hydrogen phosphate and potassium carbonate-catalyzed one-pot synthesis of 1,4- phenylene-bis(2-amino-4H-pyran-3-carbonitrile and 2-amino-4-aryl-4H-pyran-3-carbonitrile deriva- tives has been achieved by a ...
Supported by NNSFC(No.20872046);the Fundamental Research Funds for the Central Universities(No.CCNU09A02013)
The crystal structure of the title compound (C22H17BrOs, Mr = 441.27) has been determined by single-crystal X-ray diffraction. The crystal is of orthorhombic system, space group Pna21 with a = 11.76(I), b = 14.58...
Supported by the Foundation of National Natural Science Foundation of China (No. 20862003);the Natural Science Foundation of Guangxi Autonomous Region (2010GXNSFF0130014 and 073105)
Two ethyl 3-acetamido-4-aryl-6-methyl-2-oxo-3,4-dihydropyran-5-carboxylates(3) were synthesized with high diastereoselectivities and characterized by IR,NMR and MS.The configuration of 3a was confirmed by single-cry...
Project supported by the National Natural Science Foundation of China (QT Program).
Imino Diels-Alder reactions between N-arylimines and electron-rich dienophiles provide an easy entry into the tetrahydroquinoline derivatives. [1] This imino Diels-Alder reaction has been reported to be catalyzed ...