In the traditional process, m-phenylenediamine reacts with fuming sulfuric acid at high temperature to get intermediates, and then after dehydration occurs intramolecular rearrangement to get 2,4-diaminobenzenesulfoni...
supported by the National Natural Science Foundation of China(21472047,91227201,91434110);the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning(GZ2016006);the Fundamental Research Funds for the Central Universities(WK1616004)
Two fluorescence "turn-on" Zn^(2+) probes were developed by introducing an anthracenyl fluorophore through the linkage of a diphenylamino moiety at the 5-position of a dipyrrin moiety.Thus,two compounds with weak fluo...
This study was supported by the Basal Research Fund Program of Institute of Forensic Science,Ministry of Public Security,China(2014JB006).
A high performance liquid chromatography tandem mass spectrometry/mass spectrometry(HPLC-MS/MS)protocol was developed for the determination of diphenylamine(DPA).Four productions of DPA were selected for qualitative a...
The title compound, methyl 2-(diphenylamino)-4-phenyl-1,3-thiazole-5-carboxylate, was synthesized and studied by single-crystal X-ray diffraction method. The structure of the product was confirmed by IR, 1H- and 13C...
The in situ ultraviolet-visible (UV-Vis) spectroelectrochemical study on the copolymerization of diphenylamine (DPA) and o-phenylenediamine (OPD) has been performed at a constant potential of 0.8 V using indium tin ox...
Gas phase dehydrocyclization of diphenylamine (DPA) to carbazole over monometallic and bimetallic 0.4 wt% Pt-based catalysts in a fixed bed reactor was studied in the presence of hydrogen at a temperature of 550 oC. A...
The interactions of p-dimethylaminobenzaldehyde(p-DAB) and potassium hydrogen sulphate(PHS) in equimolar ratio with various concentration of diphenylamine(solid test material) have been investigated by capillary spot-...
Supported by the National Natural Science Foundation of China (Grant No. 20772006);the Program for New Century Excellent Talents in University (Grant No. NCET-07-0011);the Development Program for Distinguished Mid-Youth Teachers of Beijing Institute of Technology
The electronic effect of diphenylamine-linked bis(oxazoline) ligands was tuned through introduction of electron-withdrawing bromo and nitro substituents onto the 4 and 4′ position. The variation of the NH bond acidit...