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financially supported by the National Natural Science Foundation of China(No.51973126);the State Key Laboratory of Polymer Materials Engineering(No.sklpme20222-11)。
For decades,the preparation of polyisoprene rubber that can match the comprehensive properties of natural rubber(NR)has been pursued.While sacrificial bonds have been used to promote the strength and toughness of rubb...
financially supported by the National Natural Science Foundation of China(No.U1862206);Jilin Province Department of Education(No.JJKH20200665KJ);Dr.W.Zhao thanks for the financial support from China Postdoctoral Science Foundation(No.2021M701818);Shandong Provincial Natural Science Foundation,China(No.ZR2022QE237);Qingdao Postdoctoral Applied Research Project,PetroChina Company Limited(No.2020B-2711);H.Liu sincerely acknowledges the financial support from the Taishan Scholars Program。
Through neodymium-mediated coordinative chain transfer copolymerizaiton(CCTcoP),polyisoprenes bearing dual hydroxylated mini-blocky chain-ends were prepared via a three-step strategy.Kinetic studies revealed that,the ...
financially supported by the National Natural Science Foundation of China (Nos. 21922308 and 22005196);the Youth Innovation Promotion Association of CAS (No. Y201908)。
The polymorphic transition of trans-1,4-polyisoprene(TPI) during stretching was investigated by in situ wide-angle X-ray diffraction and Fourier transform infrared spectroscopy. The influences of the initial structure...
financially supported by the National Natural Science Foundation of China(Nos.51973126 and 51333003)。
The branching structures in natural rubber(NR) were believed to be critical for its superior mechanical properties. However, it is challenging to unravel the branching structure-function relationship of NR due to the ...
The epoxidation of polydienes yields materials with improved properties, which can be tuned by the control of the epoxidation degree. In this work, we retake a known process, the epoxidation of polyisoprene, by a diff...
financially supported by the National Basic Research Program of China(No.2015CB654700(2015CB654703));the National Natural Science Foundation of China(Nos.51673065,51703064,51473050 and 51333003);Fundamental Research Funds for the Central Universities(No.2017PY006)
Although bioinspired sacrificial bonds have been demonstrated to be efficient in improving the mechanical properties of polymer materials, the effect of binding energy of a specific dynamic bond on the ultimate mechan...
Eucommia ulmoides, also called hardy rubber tree, is an economically important tree; however, the lack of its genome sequence restricts the fundamental biological research and applied studies of this plant species. He...
financially supported by the National Natural Science Foundation of China(No.51403216)
The polypropylene-grafl-polyisoprene (PP-g-PIP) copolymers with different side chain length were synthesized by the combination of solid phase graft and anionic polymerization. The copolymers were characterized by n...
financially supported by the National Basic Research Program of China(Nos.2015CB654700(2015CB654706));the National Natural Science Foundation of China(No.51473083);Special Foundation of Taishan Mountain Scholar Constructive Program;Shandong Provincial Key R & D program(No.2015GGX102019);Shandong Provincial Natural Science Fund for Distinguished Young Scholars(No.JQ201213);the Yellow River Delta Scholar program(Office of National University Science & Technology Park Administrative Committee(China University of Petroleum)
Trans-1,4-polyisoprene(TPI) nanofibers have been fabricated successfully through electrospinning technology.Through the control of electrospinning parameters, highly crystallized TPI fresh fibers composed mainly of ...
financially supported by the National Basic Research Program of China(No.2010CB934700)
The viscoelastic properties of synthetic polyisoprenes (PI) reinforced by white carbon black (WCB) have been investigated and compared with WCB reinforced natural rubber (NR), including cure characteristics, phy...