supported by the Intergovernmental International Cooperation of the National Key R&D Program of China(2022YFE0105300);the National Natural Science Foundation of China(21790374, 22276130, 22176139, 21825601);the New Cornerstone Science Foundation through the XPLORER PRIZE。
The development of adsorbent materials for effective capture of radioactive iodomethane(CH_(3)I) from the off-gas of used nuclear fuel reprocessing, remains a significant and challenging line of research because curre...
supported by the National Natural Science Foundation of China(21971093);the Fundamental Research Funds for the Central Universities(lzujbky-2021-sp53);the International Joint Research Centre for Green Catalysis and Synthesis(2016B01017);the 111 Project。
Iodomethane is usually used as an electrophilic methylation reagent.Herein,we report its use as a C1 organocatalyst for the aerobic ortho-selective trifluoromethylation of pyridines in the absence of a transition meta...
supported by the Ministry of Science and Technology of China(2020YFA0714602);the National Natural Science Foundation of China(21722308,22003072);CAS Instrument Development Project(Y5294512C1)。
Exploring metal cluster reactivity with alkyl halides enables to understand the related chemical mechanism of metal surfaces in terms of active sites.Here we report a study of Ag_(n)^(+)(n=1-27)clusters reacting with ...
Supported by the National Natural Science Foundation of China (No. 20763007)
The reaction mechanisms of carcinogenic methylating agent iodomethane (MeI) with keto and enol tautomers of thymine (K- and E-thymine) were studied by using the B3LYP/6-311+G (d, p) method in water phase. The s...
Pentafluoroethane (HEC-125) and trifluoroiodomethane (CF3I) are considered as promising refrigerant alternatives, especially as components in mixtures, to replace CFCs or HCFCs. Effective uses of HFC-125 and CF3I requ...