BISPHOSPHINE

作品数:5被引量:13H指数:3
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相关领域:理学更多>>
相关作者:董秀琴更多>>
相关机构:武汉大学更多>>
相关期刊:《Chinese Journal of Chemistry》《Chinese Journal of Polymer Science》《Chinese Chemical Letters》更多>>
相关基金:国家自然科学基金中国科学院“百人计划”国家杰出青年科学基金国家教育部博士点基金更多>>
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Facile access to chiral 4-substituted chromanes through Rh-catalyzed asymmetric hydrogenation
《Chinese Chemical Letters》2020年第7期1859-1862,共4页Lin Tao Qingyang Zhao Xumu Zhang Xiu-Qin Dong 
the National Natural Science Foundation of China(Nos.21432007,21502145,21602172);Wuhan Morning Light Plan of Youth Science and Technology(No.2017050304010307);the Fundamental Research Funds for and the Central Universities(No.2042018kf0202);Shenzhen Nobel Prize Scientists Laboratory Project(No.C17783101);Science and Technology Innovation Committee of Shenzhen(No.KQTD 20150717103157174);SZDRC Discipline Construction Program;The Program of Introducing Talents of Discipline to Universities of China(111 Project)。
Rh/ZhaoPhos-catalyzed asymmetric hydroge nation of a series of(E)-2-(chro man-4-ylidene)acetates was successfully developed to prepare various chiral 4-substituted chromanes with high yields and excellent enantioselec...
关键词:Chiral 4-substituted chromanes Asymmetric hydrogenation Excellent enantioselectivity Gram-scale synthesis Bisphosphine-thiourea ligand 
Ethylene Polymerization and Copolymerization with Polar Monomers by Benzothiophene-bridged BPMO-Pd Catalysts被引量:6
《Chinese Journal of Polymer Science》2020年第6期579-586,共8页Hong-Liang Mu Jun-Hao Ye Guang-Lin Zhou Kang-Kang Li Zhong-Bao Jian 
the National Natural Science Foundation of China(No.21871250);the Jilin Provincial Science and Technology Department Program(No.20190201009JC);Shaanxi Provincial Natural Science Basic Research Program-Shaanxi Coal and Chemical Industry Group Co,Ltd.Joint Fund(No.2019JLZ-02).
A series of new bisphosphine-monoxide(BPMO)ligands based on benzothiophene backbone and the corresponding palladium complexes{k2-P(O)(Ph)2-3-PR1R2-C8H4S}PdMeCl{2a:R1=R2=Ph;2b:R1=R2=2-0Me-Ph;2c:R1=R2=2-CF3-Ph;2d:Rl=Ph,...
关键词:OLEFIN polymerization BISPHOSPHINE MONOXIDE Plladium Polar MONOMERS Heteroaryl backbone 
Enantiomer-selective Living Polymerization of rac-Phenyl Isocyanide Using Chiral Palladium Catalyst被引量:4
《Chinese Journal of Polymer Science》2018年第7期799-804,共6页Jian Huang Ling Shen Hui Zou Na Liu 
financially supported by the National Natural Science Foundation of China (Nos. 51673057, 21622402, and 21574036);N. Liu thanks Anhui Provincial Natural Science Foundation (No. 1608085MB41)
We report the polymerization of phenyl isocyanides with the chiral palladium(II) initiating system. The resulting polymers with optically active properties were obtained by polymerization of the racemic isocyanide m...
关键词:Enantiomer-selective polymerization Kinetic resolution Chiral sulfinamide bisphosphine POLYISOCYANIDES Living polymerization 
Solution Structure and Behavior of Benzophenone-based Achiral Bisphosphine Ligands in Noyori-Type Ru(Ⅱ)-Catalysts
《Chinese Journal of Chemistry》2007年第8期1163-1170,共8页荆庆 SANDOVAL Christian A. 山口芳树 加藤晃一 丁奎岭 
Project supported by the National Natural Science Foundation of China, Chinese Academy of Sciences, the Major Basic Research Development Program of China (No. 2006CB806106), the Science and Technology Commission of Shanghai Municipality and Merck Research Laboratories.
We herein report on solution structural studies of Ru^Ⅱ catalysts (3a, 9) composed of achiral bisphosphine ligands (4, 8) and the enantiopure 1,2-diphenylethylenediamine (DPEN). Complete chiral induction from e...
关键词:asymmetric catalysis chiral induction NMR HYDROGENATION KETONE BISPHOSPHINE RUTHENIUM 
Ruthenium Bisphosphine Catalyst on Functionalized Silica: Novel Efficient Catalyst for Carbon Dioxide Hydrogenation to Formic Acid被引量:3
《Chinese Chemical Letters》2006年第2期261-264,共4页Yi Ping ZHANG Jin Hua FEI Ying Min YU Xiao Ming ZHENG 
the National Natural Science Foundation of China (No.20173048); the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20030335068); the Scientific Research Fund of Zhcjiang Provincial Education Department (No. 20040320) ; Zhcjiang Provincial Natural Science Foundation of China (No. Y405088).
A novel efficient catalyst for the hydrogenation of carbon dioxide to formic acid ruthenium bisphosphine on functionalized silica was in situ synthesized, affording turnover frequency (TOF) of 1190 h^-1 at 100% sele...
关键词:IMMOBILIZED RUTHENIUM silica bis(1 2-diphenylphosphino)ethane (dppe) formic acid. 
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