the National Natural Science Foundation of China(Nos.21432007,21502145,21602172);Wuhan Morning Light Plan of Youth Science and Technology(No.2017050304010307);the Fundamental Research Funds for and the Central Universities(No.2042018kf0202);Shenzhen Nobel Prize Scientists Laboratory Project(No.C17783101);Science and Technology Innovation Committee of Shenzhen(No.KQTD 20150717103157174);SZDRC Discipline Construction Program;The Program of Introducing Talents of Discipline to Universities of China(111 Project)。
Rh/ZhaoPhos-catalyzed asymmetric hydroge nation of a series of(E)-2-(chro man-4-ylidene)acetates was successfully developed to prepare various chiral 4-substituted chromanes with high yields and excellent enantioselec...
the National Natural Science Foundation of China(No.21871250);the Jilin Provincial Science and Technology Department Program(No.20190201009JC);Shaanxi Provincial Natural Science Basic Research Program-Shaanxi Coal and Chemical Industry Group Co,Ltd.Joint Fund(No.2019JLZ-02).
A series of new bisphosphine-monoxide(BPMO)ligands based on benzothiophene backbone and the corresponding palladium complexes{k2-P(O)(Ph)2-3-PR1R2-C8H4S}PdMeCl{2a:R1=R2=Ph;2b:R1=R2=2-0Me-Ph;2c:R1=R2=2-CF3-Ph;2d:Rl=Ph,...
financially supported by the National Natural Science Foundation of China (Nos. 51673057, 21622402, and 21574036);N. Liu thanks Anhui Provincial Natural Science Foundation (No. 1608085MB41)
We report the polymerization of phenyl isocyanides with the chiral palladium(II) initiating system. The resulting polymers with optically active properties were obtained by polymerization of the racemic isocyanide m...
Project supported by the National Natural Science Foundation of China, Chinese Academy of Sciences, the Major Basic Research Development Program of China (No. 2006CB806106), the Science and Technology Commission of Shanghai Municipality and Merck Research Laboratories.
We herein report on solution structural studies of Ru^Ⅱ catalysts (3a, 9) composed of achiral bisphosphine ligands (4, 8) and the enantiopure 1,2-diphenylethylenediamine (DPEN). Complete chiral induction from e...
the National Natural Science Foundation of China (No.20173048); the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20030335068); the Scientific Research Fund of Zhcjiang Provincial Education Department (No. 20040320) ; Zhcjiang Provincial Natural Science Foundation of China (No. Y405088).
A novel efficient catalyst for the hydrogenation of carbon dioxide to formic acid ruthenium bisphosphine on functionalized silica was in situ synthesized, affording turnover frequency (TOF) of 1190 h^-1 at 100% sele...