This work is supported by the National Natural Science Foundation of China(NSFC,Grant 22071016);the Program for Changjiang Scholars(Q2018046);from the Ministry of Education of the People's Republic of China,the Young Top Talents Project of Liaoning Province(No.XLYC2007059);the Fundamental Research Funds for the Central Universities(DUT22LAB609).
The introduction of carbonyl group with a high density in polyethylene backbone corresponds to polyketone materials,which features excellent mechanical strength,crystallinity,photodegradability,hydrophilicity,surface ...
a JSPS Grant-in-Aid for Challenging Research(Exploratory)(No.20K21214);Scientific Research(B)(No.22H02058);JST FOREST Program(No.JPMJFR211H);Nagase Science and Technology Foundation of which Y.Inokuma is the principal investigator;The Institute for Chemical Reaction Design and Discovery(ICReDD)was established by the World Premier International Research Initiative(WPI),MEXT,Japan.Y.Ide is grateful for a Grant-in-Aid for Early-Career Scientists grant(No.21K14597)and Scientific Research on Innovative Areas“Soft Crystals”.;Y.M.would like to acknowledge the Grant-in-Aid for JSPS Research Fellow(No.21J11228)。
Here,we report the synthesis and the chain-lengthdependent self-assembling behaviors of discrete di-,tetra-,and hexaketones terminally functionalized with hydrogen-bonding carboxyl(C1,C2,and C3)and 3-acylaminopyridine...
supported by the National Natural Science Foundation of China (Nos. 51373108 and 21574088)
In this study, we attempt to prepare a new blending system of poly(vinylidene fluoride) (PVDF) and aliphatic polyketone (POK) by melt compounding, The latter is a promising engineering plastic with comprehensive...
In this research, the morphologies, isothermal-crystallization kinetics, and spherulite growth of aliphatic polyketone/polyamide-6 blends were studied. A single glass-transition temperature (Tg) was determined, and ...
Three types of organic compounds--two carboxylic acids and an anhydride, were used as additives for polyketone (PK). The effect of the additive structure and their feed ratios on the melting temperature, crystalliza...
Supported by Tianjin Natural Science Foundation(No.07JCYBJC00600)
A series of 4,4'-disubstituted-[2,2']-bipyridines, featuring electron withdrawing/donating functional groups such as amino, chloro, nitro, ethoxycarbonyl, carboxy, methyl, methoxy and hydroxymethyl, have been syn- t...
Supported by the National Natural Science Foundation of China(No.20476080);Tianjin Natural Science Foundation(No.07JCYBJC00600)
The dipping method was devised to deposit Pd onto carbon nanotube as supported catalyst(Pd/CNT) for the copolymerization of carbon monoxide(CO) and styrene(ST) towards the formation of polyketone(PK).The Pd/CNT was ch...
The CO-ethene copolymerization has been efficiently carried out in the water/CH2Cl2 emulsion by using water insolvable Pd(II) complexes. By using the surfactant SDS very high molecular weight copolymers have been obta...
financially supported by the NSFC(Nos.91127046 and 20974078);KPCME(No.109043);SRFDP (No.200800561006);High Performance Computing Center of Tianjin University,China and National Supercomputer Center in Tianjin,China
Density functional theory has been employed to study the homogeneous catalytic copolymerization of styrene with carbon monoxide. The copolymerization reaction is catalyzed by Pd(II) coordinated with 2,2'-bipyridine...