POLYKETONE

作品数:16被引量:11H指数:2
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相关领域:理学更多>>
相关期刊:《Precision Chemistry》《塑料工业》《Chinese Journal of Polymer Science》《Modern Research in Catalysis》更多>>
相关基金:国家自然科学基金天津市自然科学基金更多>>
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Cationic Palladium Catalyzed Nonalternating Copolymerization of Ethylene with Carbon Monoxide: Microstructure Analysis and Computational Study
《Chinese Journal of Chemistry》2023年第4期417-423,共7页Shi-Huan Li Ru-Chao Pan Bai-Hao Ren Jian-Wei Yang Xiaohui Kang Ye Liu 
This work is supported by the National Natural Science Foundation of China(NSFC,Grant 22071016);the Program for Changjiang Scholars(Q2018046);from the Ministry of Education of the People's Republic of China,the Young Top Talents Project of Liaoning Province(No.XLYC2007059);the Fundamental Research Funds for the Central Universities(DUT22LAB609).
The introduction of carbonyl group with a high density in polyethylene backbone corresponds to polyketone materials,which features excellent mechanical strength,crystallinity,photodegradability,hydrophilicity,surface ...
关键词:CARBONYLATION POLYKETONE C1 resource Nonalternating ETHYLENE 
Chain-Length-Dependent Hydrogen-Bonded Self-Assembly of Terminally Functionalized Discrete Polyketones
《Precision Chemistry》2023年第1期34-39,共6页Kilingaru I.Shivakumar Yumehiro Manabe Tomoki Yoneda Yuki Ide Yasuhide Inokuma 
a JSPS Grant-in-Aid for Challenging Research(Exploratory)(No.20K21214);Scientific Research(B)(No.22H02058);JST FOREST Program(No.JPMJFR211H);Nagase Science and Technology Foundation of which Y.Inokuma is the principal investigator;The Institute for Chemical Reaction Design and Discovery(ICReDD)was established by the World Premier International Research Initiative(WPI),MEXT,Japan.Y.Ide is grateful for a Grant-in-Aid for Early-Career Scientists grant(No.21K14597)and Scientific Research on Innovative Areas“Soft Crystals”.;Y.M.would like to acknowledge the Grant-in-Aid for JSPS Research Fellow(No.21J11228)。
Here,we report the synthesis and the chain-lengthdependent self-assembling behaviors of discrete di-,tetra-,and hexaketones terminally functionalized with hydrogen-bonding carboxyl(C1,C2,and C3)and 3-acylaminopyridine...
关键词:POLYKETONE hydrogen bond helix SELF-ASSEMBLY gel 
Largely Improved Stretch Ductility and β-Form Room-temperature Durability of Poly(vinylidene fluoride) by Incorporating Aliphatic Polyketone被引量:1
《Chinese Journal of Polymer Science》2018年第11期1277-1285,共9页Shui-Qin Pu Shuo Guo Ke Wang Qiang Fu 
supported by the National Natural Science Foundation of China (Nos. 51373108 and 21574088)
In this study, we attempt to prepare a new blending system of poly(vinylidene fluoride) (PVDF) and aliphatic polyketone (POK) by melt compounding, The latter is a promising engineering plastic with comprehensive...
关键词:BLEND Aliphatic polyketone Dipole interaction Stretch ductility Uniaxially drawn β-PVDF 
Isothermal-crystallization Kinetics and Spherulite Growth of Aliphatic Polyketone/Polyamide-6 Blends被引量:2
《Chinese Journal of Polymer Science》2017年第6期782-792,共11页He-xin Zhang Seong-Rok Huh Eun-Bin Ko Byung-Sik Park Keun-Byoung Yoon 
In this research, the morphologies, isothermal-crystallization kinetics, and spherulite growth of aliphatic polyketone/polyamide-6 blends were studied. A single glass-transition temperature (Tg) was determined, and ...
关键词:POLYKETONE Polyamide-6 Crystallization kinetics Spherulite growth 
An Efficient Organic Additive to Control the Crystallization Rate of Aliphatic Polyketone: A Non-isothermal Crystallization Kinetics Study被引量:6
《Chinese Journal of Polymer Science》2017年第4期547-557,共11页He-xin Zhang Min-Jeong Park Young-Kwon Moon Eun-Bin Ko Xue-quan Zhang Keun-Byoung Yoon 
Three types of organic compounds--two carboxylic acids and an anhydride, were used as additives for polyketone (PK). The effect of the additive structure and their feed ratios on the melting temperature, crystalliza...
关键词:POLYKETONE ANHYDRIDE NON-ISOTHERMAL Crystallization kinetics 
全新热塑性塑料Polyketone脱颖而出
《塑料工业》2016年第6期16-16,共1页
2015年,韩国Hyosung公司推出的Polyketone是一种全新的热塑性塑料,其成分包括一氧化碳、乙烯和丙烯,是环保产品。这种新型半晶聚合物耐冲击、耐化学品及耐磨,并有优异的阻隔特性和防火性能。
关键词:热塑性塑料 一氧化碳 环保产品 耐化学品 防火性能 耐冲击 聚合物 丙烯 
Design and Synthesis of 4,4'-Disubstituted-[2,2']-Bipyridines for Catalyzing CO/Styrene Copolymerization with Palladium(Ⅱ)
《Transactions of Tianjin University》2015年第5期406-411,共6页郭锦棠 郁培云 王海霞 赵海洋 
Supported by Tianjin Natural Science Foundation(No.07JCYBJC00600)
A series of 4,4'-disubstituted-[2,2']-bipyridines, featuring electron withdrawing/donating functional groups such as amino, chloro, nitro, ethoxycarbonyl, carboxy, methyl, methoxy and hydroxymethyl, have been syn- t...
关键词:BIPYRIDINE CO/styene copolymerization palladium (II) complex POLYKETONE 
Synthesis of Polyketone by Copolymerization of Styrene and CO Using Carbon Nanotube-Complex Pd^(2+) Catalyst被引量:1
《Transactions of Tianjin University》2014年第2期86-90,共5页郭锦棠 肖淼 王海霞 胡光 
Supported by the National Natural Science Foundation of China(No.20476080);Tianjin Natural Science Foundation(No.07JCYBJC00600)
The dipping method was devised to deposit Pd onto carbon nanotube as supported catalyst(Pd/CNT) for the copolymerization of carbon monoxide(CO) and styrene(ST) towards the formation of polyketone(PK).The Pd/CNT was ch...
关键词:carbon nanotube supported catalyst catalytic activity COPOLYMERIZATION POLYKETONE 
The Catalytic Copolymerization of Ethene with Carbon Monoxide Efficiently Carried out in Water-Dichloromethane-Sodium Dodecylsulfate Emulsion
《Modern Research in Catalysis》2013年第3期93-99,共7页Andrea Vavasori Lucio Ronchin Giuseppe Quartarone Claudio Tortato 
The CO-ethene copolymerization has been efficiently carried out in the water/CH2Cl2 emulsion by using water insolvable Pd(II) complexes. By using the surfactant SDS very high molecular weight copolymers have been obta...
关键词:Palladium Catalyst CARBONYLATION COPOLYMERIZATION POLYKETONE 
A DFT INVESTIGATION OF THE MECHANISM FOR ALTERNATINGCOPOLYMERIZATION OF STYRENE WITH CARBON MONOXIDE CATALYZED BY Pd(Ⅱ) COMPLEXES
《Chinese Journal of Polymer Science》2012年第5期744-758,共15页Zi-dan Zhang 何学浩 Shi-chun Jiang 
financially supported by the NSFC(Nos.91127046 and 20974078);KPCME(No.109043);SRFDP (No.200800561006);High Performance Computing Center of Tianjin University,China and National Supercomputer Center in Tianjin,China
Density functional theory has been employed to study the homogeneous catalytic copolymerization of styrene with carbon monoxide. The copolymerization reaction is catalyzed by Pd(II) coordinated with 2,2'-bipyridine...
关键词:DFT CO STYRENE POLYKETONE Mechanism. 
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