supported by the Natural Science Foundation of Tianjin City of China (No.18JCJQJC47700)。
A simple and effective method for constructing highly efficient oxygen reduction catalysts with trace amount of isolated cobalt was firstly developed by the pyrolysis of Co-centered polyoxometalate@metalorganic framew...
financially supported by the National Natural Science Foundation of China(20701005 & 20701006);the Fundamental Research Funds for the Central Universitues,Postdoctoral Station Foundation of Ministry of Education(20060200002);the Testing Foundation of Northeast Normal University(NENU),Science and Technology Creation Foundation of NENU(NENU-STC07009);the Program for Changjiang Scholars and Innovative Research Team in University
Two new compounds with microporous Co3[MnMo9O32].15H2O(1) and Cu3[MnMo9O32].15H2O(2) have been synthesized,and characterized by IR,element analysis,TG and single-crystal X-ray analysis.The structure analyses reveal th...
the Nature Science Foundation of Henan Province (0611011900)
A new polyoxometalate dimer based on lacunary Wells-Dawson anion and lanthanide cation, Na14[{Nd(H2O)3 (α2-PeWt7O61)2]·17H2O, was isolated as a sodium salt under ambient conditions and characterized by IR, TG, a...
Supported by the National Natural Science Foundation of China(No20571023);Program for NewCentury Excellent Talents inUniversity of Henan Province ( No2005HANCET-02 );the Foundation of Education Department of Henan Province ( No200510475013);Natu
A novel hybrid tungstocuprate ( Ⅱ ) [ Cu (2,2'-bpy) 3 ] 2 H4 [ CuW12O40 ] · 6H2O ( 2,2'-bpy = 2,2'-bipyfidine) was synthesized via hydrothermal method and characterized using elemental analyses, IR, UV, XPS...
Project supported by the Natural Science Foundation of Fujian Province (E0310016); the Education Committee Foundation of Fujian Province (JA02176)
A hydrothermal reaction of zinc acetate with molybdenum trioxide, vanadium pentoxide, phosphorus pentoxide and 2,2?-bpy (2,2?-bipyridine) led to the title compound [Zn(2,2?- bpy)2(H2O)]2[HPMo12O40(VO)2] 1. Single-cr...
A novel compound (NH4)2Y(H2O)8[PMo10V2O40]·10H2O has been prepared in an aqueous solution and characterized by elemental analysis, IR, and TG-DTG analysis. X-ray diffraction analysis was carried out on (NH4)2Y(H2O)8 ...
the State Education Ministry, the State Personal Ministry, National Natural Science Foundation of China (20073048) and the Chine
A novel compound [(NH_4)_6][Gd_2Mo_(36)O_(112)(H_2O)_(20)]·52H_2O (1) was obtained from the reaction of (NH_4)_6Mo7O24·4H_2O with GdCl3 at pH = 1.32. The X-ray structural analysis reveals that 1 crystallizes in mono...
Project supported by the National Natural Science Foundation of China.
The natural bond orbitals and McWeeny bond orders for polyoxoanions (M6O19)Z- (M = Mo, W, Z = 2; M = V, Nb, Z = 8) have been calculated in terms of Weinhold’ s natural bond orbital theory using DV-SCC-Xa method. It i...