相关期刊:《Journal of Rare Earths》《Science China Chemistry》《Chemical Research in Chinese Universities》《Progress in Natural Science:Materials International》更多>>
financial support from the National Natural Science Foundation of China(No.22208279);Financial support from the Fuzhou University(No.0041/511095)。
A visible light-promoted fast photochemical Wolff rearrangement was developed toward synthesis ofα-substituted amides in continuous flow with the use of a photochemical oscillatory flow reactor(POFR).The control expe...
A series of b-aromatic amino substituted triazolyl ketenes were reduced at different conditions to enols and saturated alcohols, respectively. The preliminary biological tests showed that some of them exhibit good fu...
The fused heterocyclic compounds 2 : imidazo [1.2-a] pyriding 2a-c and pyrido [ 1 .2-a] pyrimidine 2d were obtained from the reaction of α-cinnamoyl ketene dibenzylthio acetals 1 with diamine. When α-cinnamoyl -a'-b...
A new method for the synthesis of substituted thiophenes was through intramolecular aldol condensation ofα-oxo ketene dibenzylthioacetals.All products were confirmed with IR, 1 H NMR and elemental analysis.
Substituted pyrazolylpyrazoles were synthesized through the reaction of hydrazine hydrate and α-oxo-(3, 5-dimethyl-1 H-pyrazole-1-ly)ketene S, S- and N,S-Acetals which were obtained from α-oxo-(3,5-dimethyl-1 H-pyra...
The title compounds 3 and 4 condensed with aromatic aldehydes to give a--aroylsicinnamoyl ketene cyclic dithioacetals 5 and 6 with sodium ethoxide as the base. The stereochemistryofs and 6 was assigned as E-configurat...
α,α'-Dicinnamoyl ketene cyclic S, S-acetals 4 were reacted with ethylenediamine to afford α,α'-dicinnamoyl ketene cyclic N,N-acetals 5. This process provides a new method for thesynthesis of 5 in high yield under ...
α, α′ -Dioxo (ester ) ketene cyclic S, S-acetais 2 were reacted withethyleneddriine to chrd α, α′-dioxo (ester)ketene cyclic N, N-acetals 3 Thisprocess provides a new method for the synthesis of 3 in gnd yteld u...
Cyclic dithioacetals of α,α-dioxo (estcr) ketene 3 were reacted with butanone to afford the Michael adducts 4, catalyZed by metal Na. This process provides a new method for the Synthesis of ring-compouds in goob yie...
The addition teaction of Grignard reagents to a-cinnamoyl ketene (1, 2-ethylene) dithioncetals 4 was examined.The results showed that the 1, 4-manner nucleoohilie attack at the cinnamoyl carbon double bond occurred. P...