Desymmetrization reactions provide a powerful approach for the construction of complex molecules. Various methods have been developed for the selective monoprotection of symmetrical diols;however, their application to...
support for this work from the research affairs of Hamedan University of Medical Sciences,Hamedan,I.R.Iran;partial support of this work by the Research Affairs Office of Bu-Ali Sina University;Center of Excellence in Development of Chemical Method(CEDCM)Hamedan,I.R.Iran
{[K.18-Crown-6]Br3}n,a unique tribromide-type catalyst,was utilized for the N-boc protection of amines and trimethylsilylation(TMS)and tetrahydropyranylation(THP)of alcohols.The method is general for the preparation o...
Polystyrene supported TiCI4 (Ps-TiCI4) and polystyrene supported FeC13 (Ps-FeC13) were prepared by coordi- nating Lewis acids with polystyrene. The catalysts were characterized by TGA, BET, SEM, IR and pyri- dine-...
the special research project of the National 973 Foundation of China(No.2006CB708606);the National Natural Science Foundation of China(No.20562010)
A simple, green and efficient method for the DHP protection of various alcohols and phenols and the subsequent removal of the corresponding protective group in the presence of a catalytic amount of the activated carbo...
A synergistic catalytic effect between copper methanesulfonate and acetic acid in tetrahydropyranylation of alcohols and phenol at room temperature under solvent free condition has been described. Both alcohols (prim...
Alcohols are selectively and efficiently protected as their tetrahydropranyl ethers in the presence of a catalytic amount of Fe(HSO4)3 in good to high yields. All reactions are performed under mild and completely he...
Project supported by the Natural Science Foundation of the Education Department of Jiangsu province (No. 03KJD150109).
In dichloromethane, the nucleophilic addition of alcohols or phenols to 3,4-dihydro-2H-pyran (DHP) was cata-lyzed effectively by gallium triiodide which was generated in situ by the reaction of gallium metal and iodin...
An easy preparation of tetrahydropyranyl (THP) ethers of alcohols and phenols with 3,4-dihydro-2H-pyran (DHP) in refluxing dichloromethane has been carried out in good to excellent yields under catalysis of anhydrous ...