MIXED-VALENCE

作品数:46被引量:19H指数:2
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Crystal Structure and Characterization of a New Mixed-valence Manganese(Ⅲ/Ⅳ) Complex: [Mn2(cyclen)2(μ-O)2](ClO4)3-4H2O被引量:1
《Chinese Journal of Chemistry》2005年第4期418-420,共3页任颜卫 李珺 张逢星 张金花 郭惠 
Reaction of Molybdenum Hexa-carbonyl with Mercapto- pyridine (PySH) or Mercapto-pyridine Oxide (PyS→O) and Crystal Structure of [Et_4N][Mo_2(PyS)_3(CO)_5]
《Chinese Journal of Chemistry》2004年第11期1291-1296,共6页庄伯涛 余佩华 黄梁仁 何玲洁 周张锋 吴克琛 
Project supported by the National Natural Science Foundation of China (No. 29733090-3) and State Key Laboratory of Structural Chemistry.
Mixed-valence dinuclear molybdenum complex [Et4N][Mo2(PyS)3(CO)5] (1) (PyS=C5H4NS) has been synthe-sized and characterized by crystallography. 1 crystallizes in monoclinic system with space group P21/c with a=1.5769(1...
关键词:mixed-valence Mo-PyS complexe synthesis crystal structure PySO 
Hydrothermal Synthesis and Properties of Open-Framework Mixed-valence Iron Phosphates IIIII21.543FeFe(PO) with Three-dimensional Structure
《Chinese Journal of Chemistry》2004年第1期55-59,共5页段丽颖 刘福臣 王恩波 李阳光 胡长文 许林 
the National Natural Science Foundation of China (No. 20171010).
The open-framework iron phosphate IIIII21.543FeFe(PO) was hydrothermally synthesized and characterized by elemental analysis, IR, EPR, XPS and single crystal X-ray diffraction analysis. The title compound crystallized...
关键词:iron phosphate open framework three-dimensional structure 
Synthesis and characterization of a new Mo-Fe-S cluster compound containing MoO_3S_3 unit and mixed-valent Mo atoms [Et_4N]_2[Mo_2Fe(CO)_4(S,O-C_6H_4-1,2)_3Cl_2]
《Chinese Journal of Chemistry》1994年第6期495-502,共8页ZHUANG, Bo-Tao LAN, An-Jian HE, Ling-Jie HUANG, Liang-RenFujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, State Key Laboratory of Structural Chemistry, Fuzhou, Fujian 350002, China 
Project supported by the National Natural Science Foundation of China.
Reaction of [Mo3(CO)7(S,O-C6H4-1,2)3]2- with FeCl2 in MeCN at 60℃ affords a new Mo-Fe-S cluster complex containing MoO3S3 unit and mixed-valeut Mo atoms, [Et4N]2[Mo2Fe-(CO)4(O,S-C6H4-1,2)aCl2] (1). 1 is characterize...
关键词:Synthesis characterization Mo-Fe-S cluster MoO3S3 unit mixed-valence. 
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