NITRENES

作品数：2被引量：1H指数：1
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Skeletal Editing of Cyclic Molecules Using Nitrenes
《Chinese Journal of Chemistry》2024年第21期2656-2667,共12页Yi-An Xu Shao-Hua Xiang Jin-Teng Che Yong-Bin Wang Bin Tan 
financial support from the National Key R&D Programof China(2022YFA1503703toB.T.and 2021YFF0701604 to B.T.);National Natural Science Foundation of China(22231004 to B.T.,22371113 to Y.-B.W.,22271135 to S.-H.X.);Guangdong Innovative Program(2019BT02Y335 to B.T.);Shenzhen Science and Technology Program(JCYJ20220818100604009 to Y.-B.W.,JCYJ20210324105005015 to S.-H.X.,JCYJ20210324104212035 to Y.-B.W.and KQTD20210811090112004 to B.T.).
Nitrenes,as neutral monovalent nitrogen-centered molecular species,can insert into various bond or remove nitrogen atoms from amines.Nitrene assisted single-atom skeletal editing,discovered decades ago,provides an eff...
关键词：NITRENES Skeletal Editing Cyclic Compounds Atom exchange Late-stage modification 
Enantioselective and Enantioconvergent Iron-Catalyzed C(sp^(3))-H Aminations to Chiral 2-Imidazolidinones被引量：1
《Chinese Journal of Chemistry》2023年第17期2065-2070,共6页Tianjiao Cui Chen-Xi Ye Jordan Thelemann Daniel Jenisch Eric Meggers 
the European Research Council(ERC)under the European Union's Horizon 2020 research and innovation programme(grant agreement No.883212).
Comprehensive Summary Enantioselective or enantioconvergent iron-catalyzed ring-closing C(sp^(3))-H aminations of N-aroyloxyurea through intermediate iron nitrene species provide chiral 2-imidazolidinones in up to 99%...
关键词：Iron Asymmetric catalysis C-H activation AMINATION NITRENES HETEROCYCLES 
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