SILSESQUIOXANES

作品数:6被引量:7H指数:2
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相关领域:理学更多>>
相关期刊:《Science China Chemistry》《Chinese Journal of Polymer Science》《International Journal of Minerals,Metallurgy and Materials》《Chinese Chemical Letters》更多>>
相关基金:国家自然科学基金中国博士后科学基金更多>>
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Synthesis of Ladder-like Polyphenylsilsesquioxanes with Fairly High Regularity Using 1,2-Ethylenediamine as Endo-template被引量:2
《Chinese Journal of Polymer Science》2015年第9期1305-1312,共8页杨雄发 Cheng Cao Zhong-hong Chen Jia Liu Meng-xian Luo 来国桥 
financially supported by the Zhejiang Provincial Natural Science Foundation(No.LY14E030008);the Commonweal Technology Application Research Project of Zhejiang Province(No.2013C31079);the National Natural Science Foundation of China(No.51353003);the China Postdoctoral Science Foundation(No.2013 M531455)
Ladder-like polyphenylsilsesquioxanes with fairly high regularity were synthesized using an endo-template 1,2-ethylenediamine at mild temperature via direct co-hydrolysis and condensation reactions in the presence of ...
关键词:Ladder-like Poly(phenyl silsesquioxanes) Endo-template. 
Preparation and anti atomic oxygen erosion properties of OPPOSS/PI composites被引量:1
《International Journal of Minerals,Metallurgy and Materials》2013年第10期994-1000,共7页Wei-ping Li Hui-cong Liu Li-li Feng 
fnancially supported by the National Natural Science Foundation of China(No.51206009)
Atomic oxygen (AO) found in low earth orbit can cause serious erosion to polyimide (PI) materials, which greatly limits their lifetime. 8-phenyl silsesquioxane (OPPOSS) was synthesized, and OPPOSS/PI composites ...
关键词:composite materials polyimides SILSESQUIOXANES atomic oxygen EROSION 
Bridged polyhedral oligomeric silsesquioxane(POSS):A potential member of silsesquioxanes被引量:2
《Chinese Chemical Letters》2012年第2期181-184,共4页Jian Kun Hu Qun Chao Zhang Shu Ling Gong 
the National Natural Science Foundation of China(No20772092);the Hubei Province Natural Science Fund for Distinguished Young Scholars(No2007ABB021) for financial support
Two novel and well-defined polyhedral oligomeric silsesquioxanes(POSS) with two same Si_8O_(12) cores and a reactive NH group, namely bridged-POSS(2a and 2b),have been prepared by the traditional 'corner-cappin...
关键词:Polyhedral oligomeric silsesquioxane Bridged POSS The corner-capping reaction Organic-inorganic hybrid 
POSS-NEODYMIUM COMPLEX{[(i-C_4H_9)_7(Si_7O_(12))Nd]_4NaCl}AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE
《Chinese Journal of Polymer Science》2009年第4期597-600,共4页孙维林 
supported by the National Natural Science Foundation(No.20674071);the Special Funds for MajorState Basic Research Projects(No.2005CB623802).
The tetrameric neodymium-silsesquioxane cage complex,{[(i-C_4H_9)_7(Si_7O_(12))Nd])4NaCl},was prepared and used as precursor for the polymerization of isoprene.When activated by AlEt_3 in the presence of TMSCl,this PO...
关键词:Incompletely condensed silsesquioxanes Metal silsesquioxanes POLYISOPRENE 
Three-dimensional configurations of organic/inorganic hybrid nanostructural blocks (I).A quantum mechanical investigation for ladder-like structure of vinylsilsesquioxane被引量:1
《Science China Chemistry》2004年第5期388-395,共8页ZHANG Xingwen1,2, HU Lijiang1, HUANG Yudong1, SUN Dezhi2 & SUN Yi3 1. Department of Applied Chemistry,Harbin Institute of Technology, HUANG Yudong, Harbin 150001, China 2. Department of Environmental Engineering, Harbin Institute of Technology, Harbin 150001, China 3. Department of Experimental Mechanics,Harbin Institute of Technology, Harbin 150001, China 
The organic/inorganic hybrid nanostructural vinylsilsesquioxanes (VSSO) were prepared from the hydrolytic condensation of vinyltrimethoxysilane (VMS). The proposed formu- las of VSSO were assigned with standard spectr...
关键词:VINYLTRIMETHOXYSILANE (VMS)  SILSESQUIOXANES (SSO)  sol-gel process  quantum mechanical calculation  MNDO. 
Cage and ladder structures of silsesquioxanes characterized by UV-MALDI-TOF mass spectrometry被引量:1
《Journal of Harbin Institute of Technology(New Series)》2003年第3期295-299,共5页尤宏 胡立江 刘琰 张兴文 张皓 
Sponsored by the Foundation of Department of Science and Technology of Heilongjiang Province
The molar mass distribution of SSO in the first generation derived from the hydrolytic condensation oftwo trialkoxysilanes, [ 3- ( Methacryloxy ) propyl ] trimethoxysilane ( MPMS ) and vinyltrimethoxysilane ( VMS ) ,a...
关键词:molar mass distribution hydrolytic condensation cage and ladder structure 
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