Project supported by the Chinese National Young Scientist Research Fund(No.29502015)and Wang Kuangcheng Scientific Award.
The chemical selectivity of a novel active manganese compound [Mn2IVμ-O)3(TMTACN)2](PF6)2 (1) in catalytic oxidation reactions depended on the structure of substrates and 1 was able to catalyze the oxidation of tolue...