supported by the National Basic Research Program of China(973-2015CB856600);the National Natural Science Foundation of China(21532009,21821002,21790330,21761142010);the Science and Technology Commission of Shanghai Municipality(17XD1404500,17QA1405200,17JC1401200);the strategic Priority Research Program(XDB20000000);the Key Research Program of Frontier Science(QYZDJSSW-SLH055)of the Chinese Academy of Sciences
Anti-Markovnikov hydroazidation of unactivated alkenes using ABX–N3 as an initiator has been developed at room temperature,wherein hydrogen azide(HN3)acts as both hydrogen and azidating agent.Notably,the HN3 reagent ...