This work was supported by the National Natural Science Foundation of China(22173010 and 21773010).
We report a density functional theory study on the ruthenium-catalyzed decarbonylative annulation of an alkyne with a six-membered hydroxychromone via C–H/C–C activation.The plausible catalytic cycles involve O–H d...
We thank the financial support from the Natural Science Foundation of Shandong Province(ZR2019MB049);the National Natural Science Foundation of China(No.21973055);The Taishan Scholar of Shandong Province(No.tsqn201812013);the Qilu Young Scholar of Shandong University are also acknowledged.
The mechanism and origins of regio-and stereoselectivities of Cu-catalyzed alkyne difunctionalization with CO_(2) and trialkyl boranes were computationally investigated.The results show that the vicinal addition to al...
supported by the National Natural Science Foundation of China(51961135104,21732006,51821006);the National Key R&D Program of China(2017YFA0303502);Natural Science Foundation of Anhui Province(2108085J08).
The recently reported Ni-catalyzed methylation–allylation of alkynes with allylic alcohols and AlMe3 reagents delivers valuable tetrasubstituted alkene units in a highly regioselective fashion.Motivated by the experi...