ALKYNE

作品数：113被引量：78H指数：4
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相关领域：理学更多>>
相关作者：张俊良李福伟夏春谷汪文龙朱婧更多>>
相关机构：华东师范大学中山大学厦门大学上海大学更多>>
相关期刊：《Carbon Energy》《Chemical Research in Chinese Universities》《Organic Chemistry Frontiers》《工业催化》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划广东省自然科学基金中国博士后科学基金更多>>
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Insight into stable,concentrated radicals from sulfur-functionalized alkyne-rich crystalline frameworks and application in solar-to-vapor conversion
《Chinese Journal of Structural Chemistry》2024年第8期65-72,共8页Jian-Rong Li Jieying Hu Lai-Hon Chung Jilong Zhou Parijat Borah Zhiqing Lin Yuan-Hui Zhong Hua-Qun Zhou Xianghua Yang Zhengtao Xu Jun He 
fundings by the National Natural Science Foundation of China(22371054,22301045);the Foundation of Basic and Applied Basic Research of Guangdong Province(2020B1515120024,2024A1515012801);Science and Technology Planning Project of Guangdong Province(2021A0505030066,2023A0505050164);Z.X.acknowledges a startup fund from A^(*)STAR(SC25/22-119116).
Organic radicals feature versatile unpaired electrons key for photoelectronic and biomedical applications but remain difficult to access in stable concentrated forms.We disclose easy generation of stable,concentrated ...
关键词：Porous coordination polymers Persistent radicals NANOGRAPHENE Photothermal conversion Solar-to-vapor conversion 
Reactivity of Fe3(CO)(12) with Alkynes R-C≡C-R＇： Syntheses and Crystal Structures of Substituted Cyclic Ketones and Carbonyl Iron Complexes
《Chinese Journal of Structural Chemistry》2017年第4期696-704,共9页索全伶 吴乐 苏倩 竺宁 高媛媛 洪海龙 解瑞俊 韩利民 
supported by the National Natural Science Foundation of China(Nos.21266019,21062011 and 21462029);Inner Mongolia Autonomous Region Higher Scientific Research Project(NJZY14060)
The reactivity of carbonyl iron cluster with alkynes has been studied by the thermal reaction of Fe_3（CO）_（12） with R-C≡C-R＇（R = Fc（Ferrocenyl）; R′ = Ph（Phenyl）, Fc, H）. The hexacarbonyldiiron cluster wit...
关键词：substituted cyclopentadienone carbonyl iron complex reactivity of alkyne ferrole complex molecule and crystal structure 
One-pot Synthesis,Characterization and Crystal Structure Determination of Novel 1,4,5-Trisubstituted 1,2,3-Triazole with Two Conformational Isomers:1-Benzyl-5-((4-methoxyphenyl)ethynyl)-4-phenyl-1H-1,2,3-triazole
《Chinese Journal of Structural Chemistry》2016年第1期55-60,共6页AHMED Muhammad Naeem YASIN Khawaja Ansar KHAN Bilal Ahmad RIAZ Muhammad SADIQ-UR-REHMAN LO Kong Mun NASEER Muhammad Moazzam ARSHAD Ifzan IRSHAD Muhammad 
supported by the Higher Education Commision(HEC),Govt.of Pakistan
The title compound l-benzyl-5-（（4-methoxyphenyl）ethynyl）-4-phenyl-1H-1,2,3-triazole（C24H19N3O） was designed and synthesized using one-pot strategy and structural characterization was done by single-crystal X-ray...
关键词：click chemistry trisubstituted triazole alkyne crystal structure C–H…π interactions 
Synthesis and Crystal Structure of a B-H Activated Compound Containing a Furan Ring and an ortho-Carborane Cage
《Chinese Journal of Structural Chemistry》2013年第10期1517-1522,共6页叶红德 胡久荣 郑大贵 彭化南 叶青 部如意 燕红 
Project supported by the Science and Technology Research Project of Key Laboratory of Higher Institutions of Jiangxi Province(No.GJJl 1710);the Science and Technology Research Projects of the Education Department of Jiangxi Province(Nos.GJJ09376 and GJJ10613);the National Natural Science Foundation of China(21361022 and 21261020);the Scientific and Technological Landing Project of Higher Education of Jiangxi Province(No.KJLD12094);the Fourth Point of Specialty Construction College of Education Ministry(No.TS11524)
A new compound [CpCo（Se2C2BIoH9）CH2C（O）C4H30] has been synthesized and characterized by elemental analysis, IR spectroscopy, NMR, MS and single-crystal X-ray diffraction. The complex crystallizes in the monoclinic...
关键词：CARBORANE ALKYNE B-H activated crystal structure 
Alkynyl-modified Naphthalimide:Synthesis,Crystal Structure and Fluorescence Spectrum被引量：1
《Chinese Journal of Structural Chemistry》2009年第8期1008-1012,共5页王彬 王帅 张振兴 杨品 田野 王鹏 张奇 白钢 
supported by Tianjin Municipal Science and Technology Commission (09JCYBJC09200);National Key Basic Research and Development Program of China (973 Program, 2007CB914803)
A novel alkynyl substituted N-aryl-1,8-naphthalimide II （C20H11NO2） was synthesized for the discovery and evaluation of new fluorescence probes, and was characterized by X-ray crystal diffraction. It crystallizes in...
关键词：NAPHTHALIMIDE FLUORESCENCE ALKYNE crystal structure 
The Reaction of Octacarbonyldicobalt and Dipropargyl Malonate
《Chinese Journal of Structural Chemistry》2001年第2期104-107,共4页张玉华 劳文剑 罗资琴 殷元骐 黄子祥 吴锵金 
theNationalNaturalScienceFoundationofChina
The reaction of octacarbonyldicobalt and dipropargyl malonate afforded the two expected compounds [CH 2(CO 2CH 2C 2H\|μ) 2][Co 2(CO) 6] 2 1 and [HC 2CH 2O(O)C^CH 2CO 2CH 2C 2H\|μ][Co 2(CO) 6)] 2. Bot...
关键词：COBALT ALKYNE CARBONYL crystal structure 
Synthesis,Characterization and Crystal Structure of〔Co_2Mo_2(μ-_4-C_2HPh)(μ-CO)_4(CO)_4(η^-5C_5H_4C(O)Me)_2〕
《Chinese Journal of Structural Chemistry》1999年第5期317-321,共5页陈学年 黄小荥 等 
The reaction of μ alkyne bridged dimolybdenum compound 〔Mo 2( μ C 2HPh)(CO) 4( η 5 C 5H 4C(O)Me) 2〕 1 with Co 2(CO) 8 in refluxing toluene gave a new butterfly compound 〔Co 2Mo 2( μ 4 C 2HPh)( μ CO) 4(CO) 4( ...
关键词：SYNTHESIS crystal structure CLUSTER alkyne  bridged complex 
Synthesis and Crystal Structure of Cluster 〔C_6H_4-1,2-(CO_2CH_2C_2H-μ)_2〕〔Co_2(CO)_6〕_2
《Chinese Journal of Structural Chemistry》1999年第4期249-253,共5页陈学年 孙杰 等 
The reaction of dipropargyl phthalate C6H41,2(CO2CH2C2H)2 1 with octacarbonyldicobalt 2 resulted in the formation of red complex C6H41,2(CO2CH2C2H)2Co2(CO)62 3, in which each Co2(CO)6 group coordinates to one of t...
关键词：COBALT ALKYNE CARBONYL crystal structure 
Synthesis and Crystal Structure of μ_4-alkyne Cluster Complex (μ_4-η^(2)-C_2Ph_2) Co_4 (CO)_8 (μ-CO)_2
《Chinese Journal of Structural Chemistry》1995年第4期281-285,共5页宋礼成 申金玉 等 
The cluster complex (μ4-η2-C2Ph2) Co4 (CO)8 (μ-CO)2 was synthesized by 'one pot' method starting from Co2(CO)8 and PhCCPh in toluene and characterized by single-crystal structure analysis. It crystallizes in the mo...
关键词：crystal structure alkyne complex. cobalt complex 
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