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Study on the Synthesis and Antitumor Activity of Indolecarbazole Compounds Modified by Amino Acid and Piperidine: 《Chinese Journal of Structural Chemistry》2017年第6期918-924,共7页赵玲玲祁刚; Supported by the opening project of Jiangsu Key Laboratory of Biochemistry and Biotechnology of Marine Wetland(No.K2016-11); A series of antitumor compounds with indolecarbazole structure modified by amino acid and piperidine were designed and synthesized. The indolecarbazole parent nucleus was firstly synthesized, condensed with bromine su...; 关键词：indolecarbazole antitumor activity cytotoxin activity

Synthesis and Structure Analysis of a Tripeptide Containing N-methyl Group Amino Acid被引量：2: 《Chinese Journal of Structural Chemistry》2016年第5期718-724,共7页甄小丽马振杰田霞李营韩建荣刘守信; supported by the National Natural Science Foundation of China(No.21272052,21472034);Natural Science Foundation of Hebei Province(No.14272604D B2014208138);the Foundation of the Education Department of Hebei Province(No.ZH2012025,ZD2014017);National Basic Research Program of China(2011CB512007 and 2012CB723501); A convenient method of synthesizing a tripeptide-containing N-methyl group amino acid was developed using O-benzotriazole-N,N,N＇,N＇-tetramethyluronium-hexafluorophosphate as the condensing agent. The crystals of tri...; 关键词：tripeptide N-methyl amino acid synthesis crystal structure hydrogen bond

Synthesis and Crystal Structure of a Cu(Ⅱ) Coordination Polymer: [Cu(L)(1,10-phen)]_n被引量：1: 《Chinese Journal of Structural Chemistry》2014年第9期1300-1304,共5页王翠翠杨鸽鸽李海叶蒋毅民; supported by Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources(Guangxi Normal University),Ministry of Education of China(No.CMEMR2011-13);the Scientific research and technological development project of Guilin(No.20110330); A new complex [Cu（L）（1,10-phen）]n （1, L = N-3-pyridine sulfonyl amino acid） has been synthesized and characterized by IR, elemental analysis and X-ray diffraction analysis, and its crystal belongs to monoclinic,...; 关键词：coordination polymer Cu（Ⅱ） complex N-3-pyridine sulfonyi amino acid crystal structure

How Many Methanol Molecules Can Solvate a Glycine: a PBE1PBE Approach: 《Chinese Journal of Structural Chemistry》2011年第11期1656-1671,共16页王红磊邹昊胡勇军; supported by NNSFC (No. 20973067 and 11079020);Guangdong-NSF grants (No. 7005823);the scientific research foundation for the returned overseas Chinese scholars, State Education Ministry;the foundation for introduction of talents by the universities in Guangdong Province; Microsolvation of glycine in methanol clusters is explored by the use of DFT calculation method. The lowest energy conformations within 16.72 kJ·mol^-1 of the glycine clustering with one to six methanol molecules, wh...; 关键词：DFT MICROSOLVATION gibbs free energy amino acid GLYCINE

Syntheses and Characterization of Homochiral Three- dimensional Lanthanide-organic Frameworks Based on Ln_4O_4 Clusters and L-Aspartic Acid: 《Chinese Journal of Structural Chemistry》2011年第5期757-763,共7页李新发刘天赋高智席江忠远; supported by the Science and Technology Department of Guizhou Province (No. J[2010]2121);Zunyi Science and Technology Bureau (No. [2010]04); Four isostructural lanthanide compounds formulated as {[Ln4（μ3-OH）4（L-asp）3- （H2O）10]（ClO4）5·10H2O}n （Ln=Nd （1）, Sm （2）, Eu （3）, Gd （4）; asp=aspartic acid） were synthe- sized by a conventional solu...; 关键词：HOMOCHIRAL lanthanide cluster amino acid photoluminescence

A Series of Mononuclear Complexes Constructed from Transition Metals and Amino Acid Derived Ligands: Syntheses, Structures and Photoluminescence被引量：6: 《Chinese Journal of Structural Chemistry》2009年第11期1439-1447,共9页李新发曹荣; Supported by the 973 Program (2006CB932903, 2007CB815303);NNSFC, NSF of Fujian Province (2006F3134);"One Hundred Talent Project";Key Projects from CAS; Eight neutral mononuclear complexes constructed from transition metals （M = Co（Ⅱ）, Ni（Ⅱ）, Cu（Ⅱ）, Zn（Ⅱ）, Cd（Ⅱ）） and ligands N-（2-pyridylmethyl）-L-phenylalanine （L-Hpmpa） and N-（2-pyridylmethyl）-L...; 关键词：amino acid zinc complex cadmium complex PHOTOLUMINESCENCE

A 3D Supramolecular Framework Based on 1D {[Co(proH)(H_2O)_3]_2[P_2Mo_5O_(23)]}_n Chains and 1D Helical Water Chains: 《Chinese Journal of Structural Chemistry》2009年第11期1513-1518,共6页吴小园匡小飞余荣民卢灿忠; supported by the Natural Science Foundation of Fujian Province (2006L2005, 2006F3135, 2006F3141, 2007HZ0001-1); A three-dimensional supramolecular architecture, {[Co（proH）（H2O）3]2[P2Mo5O23]}·7H2O （1, pro = praline）, has been synthesized and characterized by IR, elemental analysis, thermogravimetric analysis, and single-c...; 关键词：POLYOXOMETALATES diphosphopentamolybdate amino acid hefical water chain

Conformation Diversity of Complexes Constructed by N-(2-Pyridylmethyl)-phenylalanine and Zn(Ⅱ)被引量：1: 《Chinese Journal of Structural Chemistry》2009年第1期53-60,共8页李新发刘庆燕谢在来李涛海李亚峰曹荣; Supported by 973 Program (2006CB932900);NNSFC (90206040, 20325106, 20521101);NSF of Fujian Province (2005HZ01-1, E0520003, 2005J058, 2006F3134);"The Distinguished Oversea Scholar Project" and "One Hundred Talent Project" from CAS; Four configurationally and conformationally related Zn（II） complexes with a tridentate ligand namely, N-（2-pyridylmethyl）-phenylalanine （Hpmpa）, have been synthesized by hydrothermal reactions. [Zn（L-α-pmpa）2...; 关键词：zinc Complex amino acid CONFORMATION configuration ISOMERISM

Correlation Study on Sweetness of Amino Acid with Different Configurations and Quantum Chemical Parameters: 《Chinese Journal of Structural Chemistry》2006年第5期589-593,共5页LIJun-Ling GU Jun QIU Guang-Min; Quantum chemical parameters of 10 amino acids with D- and L-configurations were firstly calculated with semi-empirical AM1 method. Furthermore, the relationship between molecular structures of D-, L-amino acids and t...; 关键词：amino acid SWEETNESS AMI semi-empirical method quantum chemical parameter

Syntheses and Crystal Structures of Three Novel Amino-acid-containing Polyoxomolybdosilicates: 《Chinese Journal of Structural Chemistry》2006年第3期305-311,共7页高水英曹荣李星林郑忠; This work was supported by the National Natural Science Foundation of China (50472021) and the "One-hundred Talent "Project from the Chinese Academy of Sciences; Three novel amino acid salts of 12-molybdosilicate formulated （Gly）6H4SiMo12O40·8H2O 1, K3（HGly）SiMol2O40·4H2O 2 and K2（HGly）2SiMo12O40·9H2O 3 （Gly = NH3CH2COO） were synthesized and characterized by elemen...; 关键词：POLYOXOMETALATE amino acid crystal structure

AMINO_ACID