supported by the National Foundation for Science of China (No. U1804131 and 21671114);Foundation for Science&Technology Innovation Talents in Henan province (No. 16410010012)
A new manganese coordination polymer(CP)has been synthesized under hydrothermal conditions.It’s formula is{Mn2(Oaobtc)(bpe)(H_(2)O)_(4)]}n,where H4Oobtc represents oxide azobenzene 2,2',3,3'-tetracarboxyl acid,and bp...
supported by the National Natural Science Foundation of China(21503183,21663031);the Provincial Level Innovation Programs Fund of undergraduate for 2017(No.D2017010)
One coordination polymer(CP) {[Mn(ADA)(Phen)](H2O)2}n(1, H2ADA = azobenzene-4,4'-dicarboxylic acid, Phen = 1,10-phenanthroline), has been synthesized via hydrothermal reactions. CP 1 was characterized by el...
Supported by Chongqing Postdoctoral Science Foundation (No. XM2012002)
An organic ligand and its Cu(II) complex formulated as (C13HloN203)·5H2O (H2L·5H2O, 1) and Cu(HL)2(phen)·0.125H2O (2, H2L = 4-carboxyl-4′-hydroxy azobenzene, phen = 1,10-phenanthroline) have been synth...
supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
A novel chiral methylpropargyl ester containing azobenzene moiety(S)-(-)-3-methyl-3-{4-[4-(n-octyloxy)phenylazophenyl]carbonyl}oxy-1-propyne 3(C25H30N2O3,Mr = 406.51) was synthesized and characterized by IR,NM...
This work was supported by the National Natural Science Foundation of China (No. 20573114 and 90203017);the MOST Projects of 2004CB720605 and 2006DFA43020
In this work, we report a theoretical exploration of the responses of organic azobenzene dendrimers. The polarizabilities, the first and second hyperpolarizabilities of the azobenzene monomers (GO), and the first, s...
The project was supported by the Qinglan Foundation of Jiangsu Province (HB2001-27) and the Foundation of Educational Commission of Jiangsu Province (04KJD560171)
Reaction of SmI2(THF)x with 2 equivalents of NaOAr (Ar = C6H2-tert-Bu3-2,4,6) in THF affords a divalent complex of Sm(OAr)2(THF)yTHF 1 in 90.8% yield. Treatment of 1 with 1,2-dimethoxyethane (DME) leads to t...
Qinglan Foundation of Jiangsu Province and the Foundation of Educational Ministry of Jiangsu Province
The title complex [(h5-C5H5)(THF)Sm]2[m-h2:h2-N2Ph2]22THF has been synthe- sized by the reaction of divalent (C5H5)2Sm(THF) with azobenzene and its crystal structure was determined by single-crystal X-ray diffraction ...
This work was supported by the Natural Science Foundation of Shaanxi Province (No. 01JK080 and 02JS40).
Trans-2,2?,4,4?-tetramethyl-6,6?-dinitro azobenzene (C16H16N4O4, Mr = 328.32) was isolated from benzene extract of the leaves of Aconitum sungpanense Hand. Mazz. as a new compound, and characterized by spectral method...