Supported by Sichuan Application Basic Foundation (2009JY0075)
The title complex L3Y(L = [O-4,6-di-tBu-C6H2-2-CH{CH(iPr2NCHCHN) }]) has been synthesized by the reaction of LiY[N(iPr) 2]4 with H2LCl and LiBu in a 1:3:2 molar ratio at 0 ℃ in THF,and characterized by single...
Project supported by the National Natural Science Foundation of China (20604023);Zhejiang Provincial Natural Science Foundation (Y406301)
The reaction of 2, 6-^iPr2CbH3NHSiMe3 with Tb(CH2SiMe3)3(THF)2 in benzene at room temperature afforded a binuclear terbium complex Tb2 {μ-CH2 SiMe2 NC6 H3 ^iPr2 -2, 6}3(THF)3. X-ray diffraction revealed that Tb...
Eighteen possible isomers of C78(CH2)2 weTe investigated by the INDO method. It was indicated that the most stable isomer was 42,43,62,63-C78(CH2)2, where the -CH2 groups were added to the 6/6 bonds located at the...