Supported by the National Natural Science Foundation of China (No. 20773129)
A new tetracopper complex [Cu(H2O)3Cu(HCDTA)]2(ClO4)2·H2O (CDTA = transcyclohexane-1,2-diamine-N,N,N′,N′-tetraacetate) has been prepared and characterized by singlecrystal X-ray diffraction analysis. The cr...
Supported by the National Natural Science Foundation of China (Nos 20801004/B01, 20871016/B0101, 10876002/A06);the 111 Project (B07012);Excellent Young Scholars Research Fund of Beijing Institute of Technology (No 2006Y0715)
The title complex {[AgL]ClO4}n(L=2,5-bis(3-pyridinylmethylthio)-1,3,4-thiadiazole) was synthesized by the reaction of Ag(I) salt and a novel flexible ligand L.Its structure was determined by X-ray crystallograph...
supported by the National Natural Science Foundation of China (Nos 20471026 and 20771054);the Henan Tackle Key Problem of Science and Technology (No 0524220001)
A novel complex [Na(NIT-1'-MeBzIm)3]ClO4 (NIT-1'-MeBzIm = 2-{2'-[(1'- methyl)benzimidazolyl]}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been prepared and structurally characterized by elemental anal...
the Foundation of Education Committee of Hunan Province (06C195);the Research Award Fund for Outstanding Young Teachers of Hengyang Normal University (2006);the construct program of the Key Discipline in Hunan Province
One new cadmium complex [Cd(phen)3]·(ClO4)2·(p-MBA)2·(H2O)2 has been hydrothermally synthesized by reacting p-methylbenzoic acid (p-MBA), 1,10-phenanthroline (phen) and cadmium perchlorate. It crystalli...
This work was supported by the National Natural Science Foundation of China (No. 20471026);Natural Science Foundation of Henan Province (No. 0511022600)
Two new transition metal complexes, [Ni(bipy)2Cl]·ClO4 (bipy = 2,2'-bipyridine) 1 and [Zn(bipy)2Cl]·BF4 2, have been synthesized and characterized by single-crystal X-ray diffraction analysis. Both 1 and 2 cr...
The project was supported by the Education Foundation of Jiangsu Province (03KJD150212)
The title complex [Cu(HTren)Cl2]ClO4·H2O (Tren = tris(2-aminoethyl)amine) was synthesized by the reaction of Cu(ClO4)2·6H2O with Tren.3HCl in water and methyl alcohol. The crystal (CuC6H21Cl3N4O5) is of tr...
Supported by the Foundation of Education Committee of Hunan Province (No. 05C001)
A new nickel(Ⅱ) coordination complex [Ni(2,2'-bipy)2(ClC6H4COO)(H2O)](ClO4) was synthesized by self-assembly reaction of m-chlorobenzoic acid, 2,2'-bipy and Ni(ClQ4h·6H2O. The crystal of the title compo...
This project was supported by the Foundation of Science Committee of Jiangsu province (BK2005045)
The title complex [Cu(ampym)(bapa)Cl](ClO4) (C10H22Cl2CuN6O4) was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The crystal crystallizes in the orthorhombic syst...
A dinuclear manganese(Ⅱ) complex, [Mn2(μ-OAc)2(phen)4](ClO4)2 1 (phen = phenanthroline), has been prepared by the reaction of Mn(OAc)2-4H2O, phen, tartaric acid and NaClO4·H2O in MeOH/H2O solution. The ...
This work was supported by the National Natural Science Foundation of China (No. 20271043) and Natural Science Foundation of Shandong Province (No. Y2002B10)
The mono-nuclear complex [Cdq3][Cd(qH)3](ClO4)CH3OH has been synthesized by 8-quinolinol and hydrated cadmium perchlorate in methanol solution. The crystal belongs to triclinic, space group P/ with a = 11.1449(15...