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Project supported by the National Natural Science Foundation of China
It is now widely recognized that coenzyme B12-dependent rearrangements are caused by homolytic dissociation of the Co-C bond giving rise to a 5’-deoxyadenosyl radical. The Co-C bonding strength is related ...
Project supported by the National Natural Science Foundation of China.
Ⅰ. INTRODUCTIONIn our previous studies the cleavage reaction of Co—C bond of RCo(Salen) L [Salen=bis (salicyladehyde)ethylenediamine, L= H2O or without H2O, R= CH3·, C2