CYCLOPENTADIENYL

作品数:69被引量:22H指数:2
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  • 期刊=Journal of Rare Earthsx
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Synthesis, Characterization, and Reactivity of Amine Bis(phenolato) Cyclopentadienyl Lanthanide Complexes被引量:1
《Journal of Rare Earths》2007年第5期544-548,共5页周兰芝 王余明 姚英明 张勇 沈琪 
Project supported by the National Natural Science Foundation of China (20472063);the Key Laboratory of Organic Synthesis of Jiangsu Province
(C5H5)3Ln(THF)reacted with amine bis(phenol) LH2 [ L = Me2NCH2CH2N {CH2-(2-O-C6H2-But^1-3-Me- 5)}2 ] in a 1:1 molar ratio in THF to generate the amine bis(phenolato) cyclopentadienyl lanthanide complexes LL...
关键词:inorganic chemistry amine bis(phenolate) lanthanide complex crystal structure rare earths 
Reaction of Bis(Methylcyclopentadienyl) Lanthanide Amido Complex with n-Hexyl isocyanate-Synthesis and Characterization of {(MeC_5H_4)_2YbOC(NPh_2)N(n-hexyl)}_2
《Journal of Rare Earths》2005年第6期653-656,共4页郭华东 姚英明 邓明宇 张勇 沈琪 
ProjectsupportedbytheNationalNaturalScienceFoundationofChina(20272040)
Bis (methylcyclopentadienyl) lanthanide amido complex (MeCp) 2YbNPh2 (THF) reacted with n-hexyl isocyanate (n-nexylNCO) in 1:1 molar ratio to give {(MeC5H4)2Yb[OC(NPh2)N(n-hexyl)] }2(1). Complex 1 was...
关键词:inorganic chemistry cyclopentadienyl lanthanide amido complex n-hexyl isocyanate insertion reaction crystal structure rare earths 
Molecular Structure of Bicyclopentadienyl (methycyclopentadienyl) Furanto Samarium
《Journal of Rare Earths》2004年第S1期51-53,共3页刘太奇 李静莉 沈琪 
theNationalNaturalScienceFoundationofChina
The mixed tris-cyclopentadienyl tetrahydrofuranato samarium complexes bis-(cyclopentadienyl) methylcyclopentadienyl tetrahadrofuranato samarium (Ⅰ) was synthesized by reaction of (C_5H_5)_2SmCl with methyl cyclopenta...
关键词:samarium complex CYCLOPENTADIENYL molecular structure rare earths 
Synthesis and Crystal Structure of Bis(tert-butyl-cyclopentadienyl)Erbium Ethoxide, (t-BuCp)_2ErOEt
《Journal of Rare Earths》2002年第5期374-377,共4页罗云杰 姚英明 沈琪 邢彦 
ProjectsupportedbytheNationalNaturalScienceFoundationofChina ( 2 96 72 0 2 6 )
The formation of ( t BuCp) 2ErOEt was discussed. Its single crystal structure was determined by X ray diffraction. The crystal is monoclinic, P 2(1)/ c space group, a =1.0191(2), b =1.6203(5), c ...
关键词:rare earths organolanthanide tert  butyl  cyclopentadienyl ERBIUM ethoxide X  ray crystal structure 
Synthesis and Characterization of Lanthanide Complexes Involving Cyclopentadienyl and Benzohydroximic Acid Ligand
《Journal of Rare Earths》2000年第4期315-317,共3页王修然 万玉保 胡继萍 
ProjectsupportedbytheNaturalScienceFoundationoftheEducationCommitteeofAnhuiProvince (97J0 42 )
By the reaction of Cp 3Ln with HL(Cp=η 5 C 5H 5, cyclopentadienyl; Ln=Yb, Tm, Er, Ho, Dy, Gd, Pr; HL=benzohydroximic acid), seven new complexes of the general formula Cp 2LnL were synthesized. All the complexes...
关键词:rare earths benzohydroximic acid lanthanide complexes SYNTHESIS 
Preparation and Characterisation of Cyclopentadienyl Tetramethylethene-bridged Dicyclopentadienylsamarium(Ⅲ)Tetrahydrofuranate Complexes
《Journal of Rare Earths》1994年第2期138-141,共4页孙超德 陈文启 
The complexes of cyclopentadienyl tetramethylethenebridsied dicyclopentadienylsamarium (Ⅲ) tetrahydrofuranates, Me4C2(C5H4)2LnC5H5 (THF) (Ln = Nd, Sm, Gd, Yb) were synthesized and characterized by elemental analysis,...
关键词:Bridged dicyclopentadiene Lanthanide complex Synthesis Crystal structure 
A New Synthetic Route to Di-η~5-Cyclopentadienyl Ytterbium(Ⅱ)Tetrafuranate (η~5-C_5H_5)_2Yb(THF)_2 and Its Crystal Structure
《Journal of Rare Earths》1992年第2期88-92,共5页夏巨松 卫革成 金钟声 陈文启 薛万川 
In recent years,the organometallic ehemistry of the lanthanide metals in low oxidation states has beenactively investigated.The synthesis of the low一valent lanthanide eomPlexes has the signifieant meanings ontheory a...
关键词:Yb and Its Crystal Structure Cyclopentadienyl Ytterbium Tetrafuranate A New Synthetic Route to Di C5H5 THF 
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