support from the National Natural Science Foundation of China (Nos.21372250,21121062,21302203,20732008,21772037,21772226,21861132014,91956115,and 22171078).
A copper-catalyzed[5+1]cycloaddition reaction of terminal alkynes with diazo esters for the rapid construction of protected naphthalen-1(2H)-one derivatives in moderate to good yields has been disclosed along with goo...
A novel generation of oxazole vlide and interception with sulfonamide have been well developed to construct fully substituted amidines. This copper-catalyzed four-component reaction incorporates two diazo molecules to...
An efficient synthetic method for diarylmethylphosphonates is presented.A series of phosphonate derivatives with diverse functional groups can be accessed via a rhodium catalyzed cross-coupling reaction between a-diaz...
A copper-mediated deuterotrifluoromethylation of α-diazo esters under the promotion of deuterium oxide (D20) has been developed for the synthesis of deuterium-labeled trifluoromethyl compounds. This deuterotrifluor...
Project supported by the National Natural Science Foundation of China (No. 90101018) and the Center of Materials Analysis of Nanjing University.
Five novel azo calix[4]arenes were reported. The p-aminobenzaldehyde was diazotized with sodium nitrite in aqueous hydrochloride solution. Mono-, bis-, tris- and tetrakis(p-formylphenyl)azo calix[4]arenes (including p...
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .90 10 10 18)andtheFoundationofStateKeyLaboratoryofBioorganicandNaturalProductsChemistryinShanghaiInstituteofOrganicChemistry ,ChineseAcademyofSciences .
A novel method for the preparation of chromogenic calixarenes with azo groups was reported. p-Substituted (-NO 2, -CH 3, -Cl) anilines were diazotized with isoamyl nitrite in EtONa/EtOH under refluxing condition. F...