supported by the National Natural Science Foundation of China (21772140, 21771136);Natural Science Foundation of Jiangsu Province (BK20171213);the Priority Academic Program Development of Jiangsu Higher Education Institution;the Project of Scientific and Technologic Infrastructure of Suzhou (SZS201905)
The utilization of 2,6-bis(imidazo[1,5-a]pyridin-3-yl)pyridine(bipp)and 3-(pyridin-2-yl)imidazo[1,5-a]pyridine(pip)in the compounds of manganese(Ⅱ)and copper(Ⅰ)ions is presented.Two complexes,[Mn(bipp)(SO_(4))(H_(2)...
supported by the National Natural Science Foundation of China (Nos. 21671093 and 21701078)
Two novel polynuclear complexes{NaFe4(μ4-O)(L)4(μ2-Cl)[Fe(CN)_(5)NO](H_(2)O)(DMF)_(2)}(1)and{NaFe_(4)(μ4-O)(L)_(4)(μ2-OEt)[Fe(CN)_(5)NO](H_(2)O)(DMF)_(2)}(2)have been prepared using the tetradentate N-(2-hydroxy-e...
Supported by the National Natural Science Foundation of China(No.21961027,21461020);the Natural Science Foundation of Ningxia(No.2019AAC03071);the National First-rate Discipline Construction Project of Ningxia(Chemical Engineering and Technology)(NXYLXK2017A04)。
Two new coordination compounds[Co(FDC)_(2)(H_(2)O)_(2)]_(n)(1)and[Cu(FDC)_(2)(2,2?-bpy)]·DMF·H_(2)O(2)(HFDC=9-fluorenone-4-carboxylic acid,bpy=2,2?-bipyridine,DMF=N,N-dimethylformamide)were prepared by the reactions...
Supported by the NSF of China(No.21676258);the Scientific and Technologial Innovation Project of Shanxi Province(No.2020L0647);Innovation and Entrepreneurship Project of Taiyuan Institute of Technology(No.S202114101015);Open Foundation of Key Laboratory of Advanced Energy Materials Chemistry,Ministry of Education,Nankai University。
Two new coordination polymers(Co-CPs),namely{[Co_(8)(DCPN)_(4)(1,2-bimb)4(μ_(3)-OH)_(4)]·(CH_(3)CN)_(0.5)(H_(2)0)_(2)}n(1)and{[Co_(2)(DCPN)(1,3-bimb)(μ_(3)-OH)]H_(2)0}n(2),where H3DCPN=6-(3,5-dicarboxyl-phenyl)nico...
Supported by the National Natural Science Foundation of China(No.21201144);the Natural Science Foundation of Fujian Province(No.2018J07006)。
Two isostructural tellurite phosphates Ni_(2)M^(Ⅱ)Te^(Ⅳ)_(2)O_(2)(PO_(4))_(2)(OH)_(4)(M^(Ⅱ)=Ni,Zn)have been synthesized via hydrothermal method.Both of them crystalize in monoclinic space group C2/m(No.12).For Ni_(...
One new Mn(Ⅱ)coordination polymer,[Mn(Htia)_(2)(H_(2)O)_(2)]_(n)·2nH_(2)O(1,H_(2)tia=4-(1,2,4-triazol-1-yl)isophthalic acid)has been synthesized in mixed solvents under solvothermal conditions.Further characterizati...
Supported financially by Suqian Sci&Tech Program(No.K201911);the second batch of university-level scientific research platform of Suqian University(No.2021pt04)。
Two novel copper carboxyly-phosphonates,namely,Cu2.5(5-pnc)(SO_(4))0.5(OH)(H_(2)O)0.5(1)and Cu0.5(5-pncH2)(H2O)1.5(2)(5-pncH3=5-phosphono-1-naphthalenecarboxylic acid),have been synthesized and characterized by X-ray ...
the National Natural Science Foundation of China(No.21373178)。
Two new complexes[Co_(2)(L)(4,4´-bip)(H_(2)O)_(3)]_(n)(1)and{[Co(L´)_(2)(phen)]·2H_(2)O)}_(n)(2)(H_(4)L=1-(3,5-dicarboxybenzyl)-3,5-pyrazole dicarboxylic acid,H_(3)L´=1-(3,5-dicarboxybenzyl)-3-pyrazole carboxylic ...
Supported by the Natural Science Foundation of Yan’an University (YDY2017-08);Innovation and Entrepreneurship Training Program of College Students of China (S202010719031);the Natural Science Foundation of Yulin (CXY-2020-065);the National Natural Science Foundation of China (21763028)。
One hexanuclear cobalt cluster [Co_(2) ^(Ⅲ)Co_(4) ^(Ⅱ)(L)_(4)(CH_(3) COO)_(2)(MeO)_(4)]·MeOH(1) was synthesized by the reaction of H_(2)L(H_(2)L=2-((2-hydroxy-4-methoxy-benzylideneamino)methyl)phenol) and Co(OAc)2...
supported by the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province(MO20K05);the Foundation of Key Laboratory of Functional Organometallic Materials;University of Hunan Province。
A new europium(Ⅲ)complex Eu(C_(20)H_(14)O_(3)N)_(3)(2,2'-bipy)(H2O)·H2O has been synthesized with2-diphenylanine carbonyl benzoic acid and 2,2'-bipyridine as ligands.Crystal data for the complex are as follows:tricl...