support of the National Natural Science Foundation of China(Nos.22076187,22122609);the Hunan Province Natural Science Foundation of China(No.2023JJ40530);the Scientific Research Fund of Hunan Provincial Education Department(No.22C0202);The National Science Fund for Distinguished Young Scholars(No.21925603)。
Four novel compounds based on hexanuclear thorium cluster were synthesized and characterized.Compound 1[Th_(6)(HPy C)_(8)(HCOO)_(4)]is formed by replacing formate ligands of preassembled thorium cluster[Th_(6)O_(4)(OH...
financial support from the National Natural Science Foundation of China (NSFC, Nos. 21971040, 21971039 and 21773029)。
The integration of lanthanide(Ln)ions and polyoxoniobates(PONbs)is challenging,and the know Ln-substituted PONbs are still scarce.This work introduces high-nuclear iso-Ln-oxo clusters into th PONb system.The first ser...
supported by Natural Science Foundation of Jiangsu (No. BK20191359);the Natural Science Foundation of China (No. 21571103);the Postgraduate Research & Practice Innovation Program of Jiangsu Province (No. KYCX22_1343)。
Chemical fixation of CO_(2)into C1 source, as a general approach, can effectively alleviate the emission of greenhouse gasses. Whereas, the challenge posed by the need for efficient catalysts with high catalytic activ...
Photosynthesis in nature has been deemed as the most significant biochemical reaction,which maintains a relatively stable content of O_(2) and CO_(2) in the atmosphere.Herein,for a deeper comprehension of natural phot...
financially supported by the National Natural Science Foundation of China (Grant Nos. 21671056 and 22071045);the Program for Science & Technology Innovation Talents in Universities of Henan Province (Grant No. 19HASTIT044);Excellent Youth Science Fund Project of Henan Province (Grant No. 202300410042)
Polyoxometalates(POMs),large oxoanions of the group 5 and 6 elements,attract attention due to their use as oxidation-stable catalysts and ligands.Different from the well-known V,Mo,and W POMs,the group V POMs of Ta as...
supported by the National Natural Science Foundation of China(nos.21671095 and 21901108)and startup funds from SUSTech.
Postsynthesis of the paramagnetic square-shaped complex{[(Tp*Me)Fe(μ-CN)_(2)(CN)][Co(dmbpy)_(2)]}_(2)(BPh_(4))_(2)·6MeCN·H2O[1,Tp*Me=tris(3,4,5-trimethylpyrazole)-borate;dmbpy=4,4′-dimethyl-2,2′-bipyridine)]by gr...
Supported by the Natural Science Foundation of Yan’an University (YDY2017-08);Innovation and Entrepreneurship Training Program of College Students of China (S202010719031);the Natural Science Foundation of Yulin (CXY-2020-065);the National Natural Science Foundation of China (21763028)。
One hexanuclear cobalt cluster [Co_(2) ^(Ⅲ)Co_(4) ^(Ⅱ)(L)_(4)(CH_(3) COO)_(2)(MeO)_(4)]·MeOH(1) was synthesized by the reaction of H_(2)L(H_(2)L=2-((2-hydroxy-4-methoxy-benzylideneamino)methyl)phenol) and Co(OAc)2...
Supported by the Innovation Platform Open Foundation for Colleges and Universities of Hunan Province(No.16k011);the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province。
Two novel bis(2-hydroxy-5-R-benzylidene)carbohydrazide dibutyltin complexes(R:Cl(T1),Me(T2))with hexanuclear and triangular frame structures were obtained by microwave-assisted solvothermal reaction of dibutyltin oxid...
financially supported by the Russian Science Foundation(No.16-13-10502)
Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO]^(4–)-type ligand were active in ethylene polymerization in the presence of Et2 AlCl/Bu2 Mg binary co-catalyst, giving high molecular weig...
Six-nuclear complexes of Platinum(II) with cleavage of a cystamine dihydrochloride by β-mercaptoethylamine with composition [Pt6(H2NCH2CH2S)8]Cl4·5H<...