HEXANUCLEAR

作品数:28被引量:24H指数:3
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相关领域:理学更多>>
相关作者:刘志亮更多>>
相关机构:内蒙古大学更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Science Bulletin》《Tungsten》《Advances in Chemical Engineering and Science》更多>>
相关基金:国家自然科学基金国家教育部博士点基金国家重点基础研究发展计划中央高校基本科研业务费专项资金更多>>
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Designed assembly of heterometallic cluster organic frameworks based on Th_6 cluster
《Chinese Chemical Letters》2024年第11期329-333,共5页Xianghe Kong Xiaoli Liao Zhenkun Huang Lei Mei Hongqing Wang Kongqiu Hu Weiqun Shi 
support of the National Natural Science Foundation of China(Nos.22076187,22122609);the Hunan Province Natural Science Foundation of China(No.2023JJ40530);the Scientific Research Fund of Hunan Provincial Education Department(No.22C0202);The National Science Fund for Distinguished Young Scholars(No.21925603)。
Four novel compounds based on hexanuclear thorium cluster were synthesized and characterized.Compound 1[Th_(6)(HPy C)_(8)(HCOO)_(4)]is formed by replacing formate ligands of preassembled thorium cluster[Th_(6)O_(4)(OH...
关键词:Actinide Hexanuclear thorium cluster Heterometallic organic frameworks Coordination chemistry Catalytic cycloaddition 
A series of high-nuclear planar equilateral triangle-shaped {Ln_(6)(μ_(3)-OH)_(6)} cluster encapsulated polyoxoniobates with frequency dependent magnetic property被引量:1
《Chinese Chemical Letters》2023年第7期360-363,共4页Zeng-Kui Zhu Ya-Yun Lin Rong-Da Lai Xin-Xiong Li Yan-Qiong Sun Shou-Tian Zheng 
financial support from the National Natural Science Foundation of China (NSFC, Nos. 21971040, 21971039 and 21773029)。
The integration of lanthanide(Ln)ions and polyoxoniobates(PONbs)is challenging,and the know Ln-substituted PONbs are still scarce.This work introduces high-nuclear iso-Ln-oxo clusters into th PONb system.The first ser...
关键词:Heteropolyoxoniobate Hexanuclear iso-Ln-oxo cluster Copper complexes Water vapor adsorption FERROMAGNETISM 
Four novel Z-shaped hexanuclear vanadium oxide clusters as efficient heterogeneous catalysts for cycloaddition of CO_(2) and oxidative desulfurization reactions
《Chinese Chemical Letters》2023年第1期478-482,共5页Jilei Wang Jiapeng Cao Zeyu Du Xiaomei Liu Jianian Li Qingdong Ping Tingting Zang Yan Xu 
supported by Natural Science Foundation of Jiangsu (No. BK20191359);the Natural Science Foundation of China (No. 21571103);the Postgraduate Research & Practice Innovation Program of Jiangsu Province (No. KYCX22_1343)。
Chemical fixation of CO_(2)into C1 source, as a general approach, can effectively alleviate the emission of greenhouse gasses. Whereas, the challenge posed by the need for efficient catalysts with high catalytic activ...
关键词:Z-shaped Hexavanadate cluster Lewis acid catalyst Cycloaddition of CO_(2) Oxidative desulfurization 
Hexanuclear ring cobalt complex for photochemical CO_(2) to CO conversion被引量:1
《Chinese Journal of Catalysis》2022年第9期2414-2424,共11页Xiangyu Meng Rui Li Junyi Yang Shiming Xu Chenchen Zhang Kejia You Baochun Ma Hongxia Guan Yong Ding 
国家自然科学基金(22075119);甘肃省自然科学基金(21JR7RA440);中央高校基本科研业务费专项资金优秀研究生项目(lzujbky-2021-it13).
Photosynthesis in nature has been deemed as the most significant biochemical reaction,which maintains a relatively stable content of O_(2) and CO_(2) in the atmosphere.Herein,for a deeper comprehension of natural phot...
关键词:PHOTOSYNTHESIS Homogeneous catalysis CO_(2)reduction reaction Density functional theory Hexanuclear ring cobalt complex 
Insight into hexanuclear peroxotantalum complexes:synthesis,characterization,and efficient catalyst for amidation reaction被引量:2
《Tungsten》2022年第2期158-167,共10页Wei-Xin Du Meng-Yuan Cheng Ke Li Ya-Chun Ma Jing-Wen Shi Dong-Di Zhang 
financially supported by the National Natural Science Foundation of China (Grant Nos. 21671056 and 22071045);the Program for Science & Technology Innovation Talents in Universities of Henan Province (Grant No. 19HASTIT044);Excellent Youth Science Fund Project of Henan Province (Grant No. 202300410042)
Polyoxometalates(POMs),large oxoanions of the group 5 and 6 elements,attract attention due to their use as oxidation-stable catalysts and ligands.Different from the well-known V,Mo,and W POMs,the group V POMs of Ta as...
关键词:Polyoxotantalate SELENIUM PEROXO Amidation reaction AMIDES 
Secondary Metal Coordination Using a Tetranuclear Complex as Ligand Leading to Hexanuclear Complexes with Enhanced Thermal Barriers for Electron Transfer
《CCS Chemistry》2021年第9期2530-2538,共9页Shihao Liu Yi-Fei Deng Zi-Yi Chen Lingyi Meng Xiaoyong Chang Zhiping Zheng Yuan-Zhu Zhang 
supported by the National Natural Science Foundation of China(nos.21671095 and 21901108)and startup funds from SUSTech.
Postsynthesis of the paramagnetic square-shaped complex{[(Tp*Me)Fe(μ-CN)_(2)(CN)][Co(dmbpy)_(2)]}_(2)(BPh_(4))_(2)·6MeCN·H2O[1,Tp*Me=tris(3,4,5-trimethylpyrazole)-borate;dmbpy=4,4′-dimethyl-2,2′-bipyridine)]by gr...
关键词:CYANIDE square HEXANUCLEAR postsynthesis electron transfer photomagnet 
A Hexanuclear Cobalt Cluster with Tetracubane-like Topology: Synthesis, Structure and Magnetic Properties
《Chinese Journal of Structural Chemistry》2021年第4期495-500,407,共7页SHI Zhen-Hai HUANG Yuan WU Yu-Ze CHEN Xiao-Li YANG Hua 
Supported by the Natural Science Foundation of Yan’an University (YDY2017-08);Innovation and Entrepreneurship Training Program of College Students of China (S202010719031);the Natural Science Foundation of Yulin (CXY-2020-065);the National Natural Science Foundation of China (21763028)。
One hexanuclear cobalt cluster [Co_(2) ^(Ⅲ)Co_(4) ^(Ⅱ)(L)_(4)(CH_(3) COO)_(2)(MeO)_(4)]·MeOH(1) was synthesized by the reaction of H_(2)L(H_(2)L=2-((2-hydroxy-4-methoxy-benzylideneamino)methyl)phenol) and Co(OAc)2...
关键词:HEXANUCLEAR COBALT tetracubane TOPOLOGY magnetic property 
Two Novel Dibutyltin Complexes with Trimers and Hexanuclear Based on the Bis(5-Cl/Me-salicylaldehyde) Carbohydrazide: Syntheses, Structures, Fluorescent Properties and Herbicidal Activity被引量:6
《Chinese Journal of Structural Chemistry》2020年第4期682-692,共11页FENG Yong-Lan ZHANG Fu-Xing KUANG Dai-Zhi YANG Chun-Lin 
Supported by the Innovation Platform Open Foundation for Colleges and Universities of Hunan Province(No.16k011);the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province。
Two novel bis(2-hydroxy-5-R-benzylidene)carbohydrazide dibutyltin complexes(R:Cl(T1),Me(T2))with hexanuclear and triangular frame structures were obtained by microwave-assisted solvothermal reaction of dibutyltin oxid...
关键词:bis(salicylaldehyde)carbohydrazidebutyltin microwave solvothermal synthesis crystal structure fluorescence properties herbicidal activity 
Binuclear and Hexanuclear Ti(Ⅳ) Complexes Supported by [OOOO]^(4–)-type Ligand for Preparing Disentangled UHMWPE被引量:2
《Chinese Journal of Polymer Science》2019年第5期471-477,共7页Vladislav A.Tuskaev Svetlana Ch.Gagieva Dmitry A.Kurmaev Viktor G.Vasil'ev Nikolay A.Kolosov Sergey V.Zubkevich Elena S.Mikhaylik Evgenii K.Golubev Galina G.Nikiforova Pavel A.Zhizhko Olga A.Serenko Boris M.Bulychev 
financially supported by the Russian Science Foundation(No.16-13-10502)
Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO]^(4–)-type ligand were active in ethylene polymerization in the presence of Et2 AlCl/Bu2 Mg binary co-catalyst, giving high molecular weig...
关键词:BINUCLEAR catalysts Titanium Ethylene ZIEGLER-NATTA polymerization UHMWPE 
Hexanuclear Complex of Platinum(II) with Cleavage Product of Cystamine Dihydrochloride by β-Mercaptoethylamine
《Advances in Chemical Engineering and Science》2016年第1期29-33,共5页Asmat N. Azizova Dilqam B. Tagiyev Shmid G. Gasimov Khudayar I. Gasanov 
Six-nuclear complexes of Platinum(II) with cleavage of a cystamine dihydrochloride by β-mercaptoethylamine with composition [Pt6(H2NCH2CH2S)8]Cl4·5H<...
关键词:Mercaptoamine LIGANDS PLATINUM Six-Nuclear Complexes Synthesis 
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