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作品数:164被引量:107H指数:4
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Structure and magnetic properties of Mn(Ⅱ)coordination polymers regulated by N-auxiliary ligands
《无机化学学报》2025年第3期587-596,共10页LIU Xiaxia MA Xiaofang GUO Luxia HAN Xianda FENG Sisi 
国家自然科学基金(No.21671124);山西工学院博士科研启动基金资助。
Two new Mn(Ⅱ)coordination polymers,namely{[Mn_(2)(HL)(phen)_(3)(H_(2)O)_(2)]·7.5H_(2)O}_n(1)and[Mn_(4)(HL)_(2)(1,4-bib)_(3)(H_(2)O)_(2)]_n(2),were synthesized under hydrothermal conditions by using Mn(Ⅱ)ions and 6-...
关键词:coordination polymers crystal structures binuclear Mnunit tetranuclear Mnunit MAGNETISM 
P-tuned FeN_(2)binuclear sites for boosted CO_(2)electro-reduction
《Journal of Energy Chemistry》2025年第2期816-824,I0018,共10页Cao Guo Sanshuang Gao Jun Li Menglin Zhou Abdukader Abdukayum Qingquan Kong Yingtang Zhou Guangzhi Hu 
financially supported by the National Natural Science Foundation of China-Yunnan Joint Fund(U2002213);Science and Technology Talent and Platform Program of Yunnan Provincial Science and Technology Department(202305AM070001);the Xingdian Talent Program of Yunnan Province;the Double-First Class University Plan(C176220100042).
The recycling of CO_(2)through electrochemical processes offers a promising solution for alleviating the greenhouse effect;however,the activation of CO_(2)and desorption of^(*)CO in electrocatalytic CO_(2)reduction(EC...
关键词:Electrocatalysis Diatomic catalyst Heteroatom doping CO_(2)reduction reaction DFT calculation 
Synthesis,crystal structure,and DNA‑binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand
《无机化学学报》2024年第12期2486-2496,共11页GUAN Xiaofen LIU Yating LI Jia HU Yiwen DING Haiyuan SHI Yuanjing WANG Zhiqiang WANG Wenmin 
山西省应用基础研究基金(No.202303021212256)资助。
Two new dinuclear lanthanidecomplexes,namely[Ln_(2)(dbm)_(2)(HL)_(2)(CH_(3)OH)_(2)]·4CH_(3)OH[Ln=Tb(1)and Dy(2),Hdbm=dibenzoylmethane]have been synthesized using prepared multidentate Schiff base ligand H_(3)L(hydrox...
关键词:binuclear lanthanide complexes crystal structures multidentate Schiff base DNA INSERTION 
Electrocatalytic Hydrogen Evolution by Binuclear Metal (M=Co,Fe,Mn) Xanthine Bridged Bis-corrole
《Chemical Research in Chinese Universities》2024年第6期1106-1115,共10页XU Shiyin CEN Jinghe YANG Gang SI Liping XIAO Xinyan LIU Haiyang 
supported by the National Natural Science Foundation of China(Nos.21671068,22005052);the Research Fund Program of Guangdong Provincial Key Laboratory of Fuel Cell Technology,China(No.FC202211).
Three binuclear metal (M=Co,Fe,Mn) xanthine bridged bis-corrole complexes were synthesized and investigated as electrocatalysts for the hydrogen evolution reaction (HER).All the prepared metal bis-corrole catalysts ex...
关键词:Electrocatalysis Bis-corrole Hydrogen evolution reaction Transition metal 
Multicolor circularly polarized phosphorescence of axially chiral binuclear platinum(Ⅱ) complexes
《Science China Chemistry》2024年第11期3757-3766,共10页Jintong Song Rui Zeng Hui Xiao Hailiang Ni Zong-Xiang Xu Haifeng Xiang 
supported by the National Natural Science Foundation of China (21871192);the Major Program of Guangdong Basic and Applied Research (2019B030302009)。
D-A charge transfer, including through-bond charge transfer and through-space charge transfer between two different electron donors(D) and electron acceptors(A), is a fundamental and powerful tool to tune the optical ...
关键词:Pt(Ⅱ)complexes organic light-emitting diodes circularly polarized phosphorescence axial chirality 
An example of binuclear ruthenium clusters anchored on poly-tungsten oxides for the photocatalysis reduction of nitrobenzene
《分子科学学报》2024年第5期427-433,共7页XIONG Lijuan ZHANG Shihao CHEN Wenjing YANG Mengnan NIU Jingyang WANG Jingping 
supported by the National Natural Science Foundation of China(22271075,22071044,22171071,21771054,and 21571050)
In this paper,we have successfully prepared an organic-inorganic hybridized Keggin-type Ruthenium-containing polytungsten oxide clusters that combines the organic ligand 2,2'-bipyridine(2,2'-bpy)with the noble metal r...
关键词:POLYOXOMETALATE RUTHENIUM nitrobenzene reduction 
Molecular engineering binuclear copper catalysts for selective CO_(2) reduction to C_(2) products
《Journal of Energy Chemistry》2024年第6期166-173,I0005,共9页Qi Zhao Kai Lei Bao Yu Xia Rachel Crespo-Otero Devis Di Tommaso 
the HUST-QMUL Strategic Partnership Research Funding(No.2022-HUST-QMUL-SPRF-03),which funded the project“Design of Binuclear Copper Electrocatalysts for CO_(2) Conversion from First Principles”;the China Scholarship Council for financial support。
Molecular copper catalysts serve as exemplary models for correlating the structure-reaction-mechanism relationship in the electrochemical CO_(2) reduction(eCO_(2)R),owing to their adaptable environments surrounding th...
关键词:Molecular catalyst design Selective CO_(2)reduction C_(2)products Density functional theory calculations 
Catalytic recycling of polyesters via a binuclear catalyst
《Science China Chemistry》2024年第2期426-427,共2页Bo Sun Ding Ma 
Plastics play a crucial role in modern society life. While the increasing use of plastics and rapid accumulation of plastic waste in nature environment have caused severe environmental crisis and the waste of carbon r...
关键词:CATALYTIC POLYESTER CATALYST 
Insertion of unnatural metal ligand in the heme pocket of nitrophorin through protein semi-synthesis:Toward biomimicking binuclear active sites
《Chinese Chemical Letters》2023年第12期132-135,共4页Yonglu Chen Yi Zhou Chunmao He 
financial support from the National Natural Science Foundation of China(Nos.22077036 and 22277029)is greatly acknowledged.
Herein,we report a semi-synthetic strategy affording a nitrophorin 2(NP2)variant with a N,N'-bis(2-pyridylmethyl)amine(Dpa)ligand as sidechain selectively installed at position 27,which was assembled from a synthetic ...
关键词:Protein semi-synthesis Protein modification Nitrophorin2 Heteronuclear active site Native chemical ligation 
Macrocyclic Binuclearα-Diimine Nickel Catalysts for Ethylene Polymerization被引量:1
《Chemical Research in Chinese Universities》2023年第5期797-802,共6页YANG Jingshuang ZHANG Yuxing JIAN Zhongbao 
This work was supported by the National Natural Science Foundation of China(No.22122110);the Science and Technology Department Program of Jilin Province,China(No.20230101347JC).
Polyolefins are globally important plastics.Molecular weight and molecular weight distribution are two key parameters for determining the properties of polyolefin materials.In this contribution,we develop a strategy f...
关键词:POLYOLEFIN Nickel catalyst Diimine ligand Macrocyclic binuclear strategy Bimodal polyethylene 
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