Two novel substituted derivatives ( μ3-S)( μ-H)Fe2Co(CO)7Ln (n=2, L=AsPh3 (3) n=1, L=dppm (4)) have been synthesized and characterized by IR, 1H NMR, 31P NMR, MS and X-ray crystallography . The cluster 4 crystallize...
The substituted reactions of (μ-FcC≡CH)Co2(CO)6 with PPh3, AsPh3 and dppm have been studied and three new substituted derivatives have been obtained. The compounds were characterized by elemental analysis, IR, 1H NM...
The mono and di substituted derivatives of the parent cluster {μ3 H(Ph)C=C}FeCo2(CO)9 (1) have been synthesized by facile substitution reactions. The compound {μ3 H(Ph)C=C}FeCo2(CO)7(dppe) (2), {μ3 H(Ph)C=C}FeCo2(C...