supported by the National Key R&D Program of China(No.2018YFA0306600);AnHui Initiative in Quantum Information Technologies(No.AHY050000)
The formation and qualification of redox sites in transition metal oxides are always the active fields related to electronics, catalysis, sensors, and energy-storage units. In the present study, the temperature depend...
supported by the National Key Basic Research Program of China(973)(2013CB921802);Fundamental Research Funds for the Central Universities,China,State Key Laboratory for Conservation and Utilization of Subtropical Agro-bioresources,China(KSL-CUSAb-2012-03)~~
supported by the National Key Basic Research Program of China(973)(2013CB921802)~~
本文研究了(C_(60))_2-[P(O)(OCH_3)]_2富勒烯双体内的笼间C―C键的热力学性质(该双体的结构详见文献,Chem.Commun.2011,47,6111)。原位、变温电子顺磁共振波谱实验结果表明,该C―C键的键离解能(BDE)为72.4 k J?mol^(-1)(17.3 kcal?mol^...