the National Natural Science Foundation of China(21376272,21476066);the Scientific Research Fund of Hunan Provincial Education Department(16B064,16C0430);Hengyang Science and Technology Project(2015KJ33,2016KG64);Hunan province college students’research learning and innovative experiment project;Key Laboratory of green functional building materials of Hunan Institute of Technology and the construct program of the key discipline in Hunan province