超高压液相色谱法测定食品接触材料印刷油墨中光引发剂  

Determination of photo-initiators in printing ink on food contact material by ultra-pressure liquid chromatography

作　　者：韩伟[1] 庞震[1] 张媛媛[1] 李宁涛[1] 王利兵[2] 

机构地区：[1]天津出入境检验检疫局工业产品安全技术中心,天津300042 [2]湖南出入境检验检疫局技术中心,长沙410004

出　　处：《食品安全质量检测学报》2013年第4期1005-1009,共5页Journal of Food Safety and Quality

基　　金：国家"十二五"科技支撑计划项目(2011BAK10B05;2012BAD29B05)~~

摘　　要：目的建立超高压液相色谱-二极管阵列检测器(UPLC-DAD)快速测定食品接触材料表面印刷油墨中光引发剂的分析方法。方法以30余种食品接触材料为原料,采用65%乙醇和正己烷作为食品模拟物模拟含酒精和脂肪食品,分别在5℃和40℃的温度下进行240h的迁移试验。迁移后的模拟液经浓缩、净化、重新溶解并过滤后直接用UPLC-DAD进行分析。结果线性范围为0.1～500.0μg/L,检出限为0.005μg/dm2,空白样品的加标回收率为79.8%～92.3%。ITX和EHDAB在食品接触材料中一般协同出现,其迁移水平分别为0.11μg/dm2和0.092～0.370μg/dm2。结论超高压液相色谱-二极管阵列检测器(UPLC-DAD)可以快速测定食品接触材料表面印刷油墨中光引发剂。Objective To establish a method for the determination of photo-initiators in printing ink on the food contact materials by ultra-pressure liquid chromatography-diode array detector (UPLC-DAD). Methods Migration test was studied using 65%of n-hexane as analog simulation of alcohol and fat food respectively, under the temperature of 5℃and 40℃in 240 h. After concentrated, purified, redissolved and filtered, the migrated si-mulating liquid was analyzed by UPLC-DAD. Results The method showed a good linearity over the range of 0.1～500μg/L, and the detection limit was 0.005μg/dm2. The recoveries were 79.8%～92.3%. ITX and EHDAB usually appeared together in food contact materials, and its migration levels were 0.11 μg/dm2 and 0.092～0.37μg/dm2. Conclusion The ultra-pressure liquid chromatography-diode array detector (UPLC-DAD) can be used for the rapid determination of photo-initiators in printing ink on food contact material.

关 键 词：食品接触材料 印刷油墨 光引发剂 迁移试验 液相色谱 

分 类 号：TS206.4[轻工技术与工程—食品科学] O657.72[轻工技术与工程—食品科学与工程]