3,5-二(氨甲基)-1,2,4-三唑的合成与表征  

Synthesis and Characterization of 3,5-Bis(aminomethyl)-1,2,4-trizole

作　　者：裘灵光[1] 田玉鹏[1] 谢复新[1] 张银汉[2] 

机构地区：[1]安徽大学化学系,安徽合肥230039 [2]中国科技大学应用化学系,安徽合肥230026

出　　处：《安徽大学学报（自然科学版）》1999年第4期75-80,共6页Journal of Anhui University(Natural Science Edition)

基　　金：国家自然科学基金!(29871001)

摘　　要：以羟基乙酸与水合肼为原料,经缩合成环、脱氨基、氯化、氨化四步反应,合成了尚未见文献报道的化合物3 ,5 - 二( 氨甲基) - 1 ,2 ,4 - 三唑(amt·2HCl) ,用元素分析、红外光谱、核磁共振氢谱和质谱等方法进行了表征。讨论了合成条件。A new compound 3,5-bis(aminomethyl)-1,2,4-trizole(amt) was synthesized in four steps from glycolic acid and hydrazine hydrate by cyclic condensation,deaminizating,chlorinating and ammoniation,and characterized with elemental analysis,IR, 1HNMR and MS. The synthetic conditions of the reaction, character of spectra and splitted rule based MS spectra were also discussed in this paper.

关 键 词：氨甲基 三唑 合成 表征 质谱 核磁共振氢谱 

分 类 号：O626.26[理学—有机化学]