皮蛋壳表层红色斑块成分的分析与鉴定  

Analysis and identification of red patch components on preserved egg shell surface

作　　者：孙静[1] 杨雪 周彬 杜华英[3] 贾鸣 李刚 杜金平[1] SUN Jing;YANG Xue;ZHOU Bin;DU Hua-ying;JIA Ming;LI Gang;DU Jin-Ping(Institute of Animal Husbandry and Veterinary Medicine,Hubei Academy of Agricultural Sciences,Wuhan 430064,China;College of Bioengineering and Food,Hubei University of Technology,Wuhan 430064,China;College of Food Science and Engineering,Jiangxi Agricultural University,Nanchang 330045,China;Hubei Agricultural Reclamation Foreign Economic Exchange Center,Wuhan 430060,China)

机构地区：[1]湖北省农业科学院畜牧兽医研究所,武汉430064 [2]湖北工业大学生物工程与食品学院,武汉430064 [3]江西农业大学食品科学与工程学院,南昌330045 [4]湖北农垦对外经济交流中心,武汉430060

出　　处：《食品安全质量检测学报》2022年第15期4883-4890,共8页Journal of Food Safety and Quality

基　　金：国家现代农业产业技术体系资助项目(CARS-42-26);湖北省动物胚胎工程与分子育种重点实验室项目(2022ZD108);湖北省农业科学院“青年拔尖人才”培养计划项目(2021)。

摘　　要：目的 分析鉴定皮蛋壳表面红色斑块物质组成成分,为控制红斑生成提供理论依据。方法 采用场发射扫描电镜(scanning electron microscope, SEM)、X射线衍射仪(X-ray diffractometer, XRD)、X射线电子能谱仪(X-ray photo-electron spectroscopy, XPS)分析皮蛋壳表面红色斑块的微观结构和化学成分。结果 皮蛋壳表面红色斑块物质是大块片状物附着在粗糙的碳酸钙晶体外层,蛋壳气孔也被块状异物堵塞,XPS检测出红斑由C、O、N、Fe、Cu、S、Mg等元素组成,Fe元素含量低,未检出Pb元素;XRD分析确定红斑的主要物质是CuO,红斑外层Cu~+因氧化而成Cu。结论 皮蛋壳表面红色斑块主成分为CuO。采取鸭蛋消毒控菌,低温避光腌制或许可控制蛋壳红斑形成。Objective To analyze and identify the components of red patch on preserved egg shell surface, and provide theoretical basis for controlling the formation of red spots. Methods The microstructure and chemical composition of red patches on preserved egg shell surface were analyzed by field emission scanning electron microscope(SEM), X-ray diffractometer(XRD) and X-ray photo-electron spectroscopy(XPS). Results The red spots on eggshell were large sheets attached to the rough outer layer of calcium carbonate crystals and eggshell stomata were also blocked by lumpy foreign bodies, XPS detected that the red patches was composed of C, O, N, Fe,Cu, S, Mg and other elements. The content of Fe was low, and Pb was not detected. XRD analysis showed that the main substance of red patches was CuO, and the outer layer of red patches Cuwas oxidized to form Cu.Conclusion The main component of red patch on preserved egg shell surface is CuO. Adopting disinfection and control bacteria of duck eggs and curing at low temperature and avoiding light may control the formation of red patch on preserved eggs shell surface.

关 键 词：皮蛋 红色斑块 成分分析 CU2O 

分 类 号：TS253.7[轻工技术与工程—农产品加工及贮藏工程]