离子迁移谱法测定饮料中的糖精钠和痕量马来酸  

Ion mobility spectrometry for the detection of sodium saccharin and trace maleic acid in beverages

作　　者：张志刚[1] 方恩华[1] 郝玉蕾 朱军[2] 

机构地区：[1]厦门出入境检验检疫局检验检疫技术中心,厦门361026 [2]厦门大学化学化工学院,厦门361005

出　　处：《食品安全质量检测学报》2015年第6期2151-2156,共6页Journal of Food Safety and Quality

基　　金：国家质检总局科研项目(2014IK111)~~

摘　　要：目的利用电喷雾-高效离子迁移谱(ESI-HPIMS)对饮料中常见的甜味剂糖精钠和有可能残存的痕量马来酸进行检测。方法通过在饮料中加入糖精钠和马来酸标准品来模拟添加剂存留情况,添加后的饮料经简单的稀释,过滤等前处理,直接进样即可测定。结果研究结果表明,仪器对糖精钠和马来酸标准品的灵敏度达到了10^(-10)数量级,最低检出限为0.1 ng/μL,6组平行数据的相对标准偏差(RSD)在1.2%~7.2%,线性相关系数均达到了r^2大于0.99,单次测量时间低于10 s。结论实现了糖精钠和痕量马来酸的快速分析检测。Objective Saccharin sodium and possible remaining maleic acid in beverages were detected by high performance ion mobility spectrometry with direct electrospray ionization (ESI-HPIMS). Methods By adding saccharin sodium and maleic acid standards into beverages to simulate real situation, the beverages were diluted, filtered, samples were injected into IMS directly. Results The research showed that the sensitivity of the instrument for saccharin sodium and maleic acid could reach 10-10 with detection of minimum standard 0.1 ng/mL, the relative standard deviation (RSD) of 6 parallel data was in the range of 1.2%~7.2%, with linear correlation coefficients r2>0.99. The single detection time was less than 10 s. Conclusion This method can achieve a rapid analysis of sodium saccharin and trace maleic acid.

关 键 词：离子迁移谱 饮料 糖精钠 马来酸 

分 类 号：TS27[轻工技术与工程—农产品加工及贮藏工程] O657[轻工技术与工程—食品科学与工程]