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机构地区:[1]苏州大学物理科学与技术学院,江苏苏州215006
出 处:《苏州大学学报(自然科学版)》2003年第4期51-56,共6页Journal of Soochow University(Natural Science Edition)
基 金:国家自然科学基金资助项目:(10175048)
摘 要:以高纯石墨作靶、CHF3/Ar作源气体,采用反应磁控溅射沉积法制备了具有低介电常数(k~2.18)的氟化非晶碳(a C:F)薄膜.薄膜的结构和性质由红外吸收光谱、紫外可见光光谱、沉积速率及介电常数等作了表征.有关数据显示,薄膜的沉积速率随着射粒输入功率的增大而上升.所沉积的a C:F薄膜中存在着一定比例的苯环结构.改变射频功率可以改变薄膜中的F/C比值,调制薄膜中环式结构与链式结构的比例,从而影响薄膜的介电常数和光学带隙等性能.The aC:F films with low dielectric constant (k2.18) were prepared by reactive magnetron sputtering with CHF3/Ar as source gases and pure graphite as a target. The bonding configurations and optical properties have been examined by Fourier transform infrared radiation,ultravioletvisible transmission spectroscopy,deposition rate and dielectric constant.It is showed that the deposition rate of the films increases with the increasing of RF input power,and the aC:F films consist of some benzene rings configuration.The F/C atomic ratio and the ratio of rings and chains configuration in the films can be modulated by changing RF input power,which has a great influence on the properties of the aC:F films,such as dielectric constant and optical band gaps.
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