supported by the National Natural Science Foundation of China (No. 21001016 and 20902112)
A Csp3-Csp3 coupling production of the original ligand molecule [(CMeN(2,6-iPr2C6H3))2]2 (1) and an antimony ionic compound with α-diimine ligand [LH3]+[SbCl4]-(2, L = [(2,6-iPrC6H3)NC(Me)]2) were synthe...
supported by the National Natural Science Foundation of China (20842006, 20972129, and 20902112);China Postdoctoral Science Foundation (20090460748);the Fund for New Teacher of Higher Education (200803841012);the Project Sponsored by SRF for ROCS, SEM (2009060011500466)
This paper reports the reactions of a monomeric aluminum dihydride LAlH2(L = HC[C(Me)N(Ar)]2,Ar = 2,6-i-Pr2C6H3) with diazo,azido,and terminal alkyne compounds.The reaction of LAlH2 with N2CH(SiMe3) and N3(1-Ad) occur...