supported by the National Natural Science Foundation of China(NSFC,21831001,21571016,91122028);the NSFC for Distinguished Young scholars(20725101)。
The synergistic effect of trivacant B-α-Ge W_(9)O_(34)fragments as structure-directing agents and inorganic B-O segments as intramolecular decoration afforded an unprecedented 28-Ni-added huge cluster K_(2)Na_(14)H_(...
This work was supported by the National Natural Science Foundation of China(Nos.21831001,21571016,91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Two new belt-like borates Na_(4)[B_(9)O_(14)(OH)_(3)]·0.5H_(2)O(1)and Na_(5)[B_(9)O_(14)(OH)_(4)](2)have been synthesized under solvothermal conditions.Both compounds contain unprecedented B_(9)O_(16)(OH)_(n)^((n+5))...
supported by the National Natural Science Foundation of China(NSFC,21831001,21571016,91122028);the NSFC for Distinguished Young Scholars(20725101)。
A new ring-shaped 12-Ti-substituted poly(polyoxometalate)(poly(POM)),K_(10)H_(15)[{K_(2)Na(H_(2)O)_(3)}@{(Ti_(2)O)_(2)(Ti_(4)O_(4))_(2)(A-α-1,3,5-GeW_(9)O_(36))_(2)(A-α-2,3,4-GeW_(9)O_(36))_(2)}]·45H_(2)O(1),has be...
This work was supported by the National Natural Science Foundation of China (Nos.21571016,21831001,91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Anew mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis...
Supported by the National Natural Science Foundation of China(Nos.21571016,21831001 and 91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Two new alkaline metal borates containing 1D{B5}/{B6}oxoboron helical chains,namely Na0.5[B5O8(OH)2]0.5[B5O6(OH)2]0.5·0.5H3O(1)and NaKCs[B6O9(OH)3](2)were synthesized under solvothermal conditions.Compound 1 contains...
supported by the NSFC(Nos.21571016,21831001 and 91122028);the NSFC for Distinguished Young Scholars(No.20725101)
A neoteric organic-inorganic hybrid Co-substituted phosphotungstate H6{[Co(en)2(OAc)2]2[Co4(H2 O)2(PW9 O34)2]}?2 H2 en?36 H2 O(1, en = enthylenediamine) has been made under hydrothermal conditions and characterized by...
supported by the National Natural Science Foundation of China(50872133);the National Natural Science Fund for Distinguished Young Scholars of China(20725101);the National Basic Research Program of China(2011CB932504);the Natural Science Foundation of Fujian Province(E0510030 & 2008F3120)
Six novel 3D layer-pillared lanthanide-transition metal coordination polymers,LnCuX(IN)2(Ac)(H2O)(Ln = Tb,X = Br(1);Ln = Er,X = Cl(2)),[LnCuCl(IN)2(Ac)].H2O(Ln = Gd(3);Ln = Eu(4)),and [LnCu2Br2(IN)2(Ac)(H2O)].nH2O(Ln ...
supported by the National Natural Science Fund for Distinguished Young Scholars of China (No 20725101);the 973 Program (No 2006CB932904);the NSF of Fujian Province (Nos E0510030 and 2008F3120);the Knowledge Innovation Program of CAS (No KJCX2YWH01);the NNSFC (No 20521101)
Two novel lanthanide-organic polymers [Er2(pdc)2(o-bdc)(H2O)2]·H2O(1,H2pdc = 2,6-pyridinedicarboxylic acid,o-H2bdc = 1,2-benzenedicarboxylic acid) and Er(Himdc)(mbdc)0.5(H2O)(2,H3imdc = 4,5-imidazoledi...
supported by the National Natural Science Fund for Distinguished Young Scholars of China (No 20725101);the 973 Program (No 2006CB932904);the NSF of Fujian Province (No E0510030);the NNSFC (No 20521101);the Research Foundation of Education Bureau of Fujian Province (No JA08053)
One new sandwich-type tetra-nickel substituted polyoxotungsate,[Ni(trien)]4-[Ni4(H2O)2(HPW9O34)2]·4H2O(1,trien=triethylenetetramine),has been hydrothermally synthesized and characterized by IR,elemental analy...