国家自然科学基金(20725101)

作品数:17被引量:11H指数:2
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相关作者:方伟慧更多>>
相关机构:中国科学院福建物质结构研究所北京理工大学更多>>
相关期刊:《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Structural Chemistry》《Science Bulletin》更多>>
相关主题:HYDROTHERMAL_SYNTHESISPOLYOXOMETALATEBORATELANTHANIDESUBSTITUTED更多>>
相关领域:理学矿业工程化学工程石油与天然气工程更多>>
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A new 28-Ni-added poly(polyoxometalate)with B atoms:synthesis,structure and catalysis for Knoevenagel condensation被引量:1
《Science China Chemistry》2023年第5期1394-1399,共6页Chen Lian Hai-Lou Li Guo-Yu Yang 
supported by the National Natural Science Foundation of China(NSFC,21831001,21571016,91122028);the NSFC for Distinguished Young scholars(20725101)。
The synergistic effect of trivacant B-α-Ge W_(9)O_(34)fragments as structure-directing agents and inorganic B-O segments as intramolecular decoration afforded an unprecedented 28-Ni-added huge cluster K_(2)Na_(14)H_(...
关键词:POLYOXOMETALATE hydrothermal synthesis high-nuclearity TMAPs knoevenagel condensation 
Two New Borates Built by Different Types of{B_(9)}Cluster Units被引量:1
《Chemical Research in Chinese Universities》2022年第3期744-749,共6页CHEN Juan WANG Jiajia CHEN Chongan YANG Guoyu 
This work was supported by the National Natural Science Foundation of China(Nos.21831001,21571016,91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Two new belt-like borates Na_(4)[B_(9)O_(14)(OH)_(3)]·0.5H_(2)O(1)and Na_(5)[B_(9)O_(14)(OH)_(4)](2)have been synthesized under solvothermal conditions.Both compounds contain unprecedented B_(9)O_(16)(OH)_(n)^((n+5))...
关键词:Oxoboron cluster SYNTHESIS BORATE Supramolecular framework Structure 
A ring-shaped 12-Ti-substituted poly(polyoxometalate):synthesis,structure,and catalytic properties被引量:1
《Science China Chemistry》2022年第5期892-897,共6页Hai-Lou Li Chen Lian Guo-Yu Yang 
supported by the National Natural Science Foundation of China(NSFC,21831001,21571016,91122028);the NSFC for Distinguished Young Scholars(20725101)。
A new ring-shaped 12-Ti-substituted poly(polyoxometalate)(poly(POM)),K_(10)H_(15)[{K_(2)Na(H_(2)O)_(3)}@{(Ti_(2)O)_(2)(Ti_(4)O_(4))_(2)(A-α-1,3,5-GeW_(9)O_(36))_(2)(A-α-2,3,4-GeW_(9)O_(36))_(2)}]·45H_(2)O(1),has be...
关键词:POLYOXOMETALATE hydrothermal synthesis Ti-oxo cluster chiral catalytic oxidation 
A New Tubular Borate Built by[B_(14)O_(24)(OH)_(6)]^(12-) Cluster Units被引量:1
《Chemical Research in Chinese Universities》2022年第1期123-127,共5页SUN Xiao-Shuang QIN Dan LI Xu-Yan YANG Guo-Yu 
This work was supported by the National Natural Science Foundation of China (Nos.21571016,21831001,91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Anew mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis...
关键词:Alkali and alkaline-earth metal BORATE Tube Solvothermal synthesis CLUSTER 
诱导聚集与协同配位策略构筑金属氧合团簇及其有机骨架
《中国科学:化学》2020年第9期975-985,共11页方伟慧 杨国昱 
国家自然科学基金(编号:21771181,21831001,21571016,91122028,20725101);中国科学院青年创新促进会(编号:2017345)资助项目。
随着金属有机骨架(metal organic frameworks,MOFs)和金属氧合团簇(metal oxo clusters,MOCs)两大领域的不断发展壮大,形成了一种新的材料—金属簇有机骨架(metal cluster organic frameworks,MCOFs).由于这种材料同时结合了金属氧合团...
关键词:氧合团簇 金属簇有机骨架 诱导聚集 协同配位 
Two New Alkaline Metal Borates with Supramolecular Framework Constructed from 1D{B5}/{B6}Helical Chains
《Chemical Research in Chinese Universities》2020年第1期86-90,共5页QIU Qiming SUN Kening YANG Guoyu 
Supported by the National Natural Science Foundation of China(Nos.21571016,21831001 and 91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Two new alkaline metal borates containing 1D{B5}/{B6}oxoboron helical chains,namely Na0.5[B5O8(OH)2]0.5[B5O6(OH)2]0.5·0.5H3O(1)and NaKCs[B6O9(OH)3](2)were synthesized under solvothermal conditions.Compound 1 contains...
关键词:Alkaline metal borate Solvothermal synthesis Helical chain Supramolecular framework 
A New 3-D Supramolecular Framework Built by Co4-Substituted Sandwiched Phosphotungstates, Organoamines and Co-Complexes: Synthesis, Structure, and Property被引量:1
《Chinese Journal of Structural Chemistry》2019年第9期1585-1592,共8页MA Wei-Dan LI Hai-Lou YANG Guo-Yu 
supported by the NSFC(Nos.21571016,21831001 and 91122028);the NSFC for Distinguished Young Scholars(No.20725101)
A neoteric organic-inorganic hybrid Co-substituted phosphotungstate H6{[Co(en)2(OAc)2]2[Co4(H2 O)2(PW9 O34)2]}?2 H2 en?36 H2 O(1, en = enthylenediamine) has been made under hydrothermal conditions and characterized by...
关键词:POLYOXOMETALATE HYDROTHERMAL SYNTHESIS 3-D SUPRAMOLECULAR framework adsorption properties 
A series of 3d-4f heterometallic frameworks comprising 2D lanthanide-organic layers and diverse Cu-complex pillars被引量:3
《Science China Chemistry》2011年第9期1407-1417,共11页XU Jing ZHENG ShouTian YANG GuoYu 
supported by the National Natural Science Foundation of China(50872133);the National Natural Science Fund for Distinguished Young Scholars of China(20725101);the National Basic Research Program of China(2011CB932504);the Natural Science Foundation of Fujian Province(E0510030 & 2008F3120)
Six novel 3D layer-pillared lanthanide-transition metal coordination polymers,LnCuX(IN)2(Ac)(H2O)(Ln = Tb,X = Br(1);Ln = Er,X = Cl(2)),[LnCuCl(IN)2(Ac)].H2O(Ln = Gd(3);Ln = Eu(4)),and [LnCu2Br2(IN)2(Ac)(H2O)].nH2O(Ln ...
关键词:3d-4f heterometallic frameworks LIGANDS hydrothermal syntheses 
Two Novel 2D Lanthanide-organic Frameworks Based on Different Carboxylate-containing Mixed Ligands被引量:3
《Chinese Journal of Structural Chemistry》2010年第1期17-22,共6页王志龙 郑寿添 杨国昱 
supported by the National Natural Science Fund for Distinguished Young Scholars of China (No 20725101);the 973 Program (No 2006CB932904);the NSF of Fujian Province (Nos E0510030 and 2008F3120);the Knowledge Innovation Program of CAS (No KJCX2YWH01);the NNSFC (No 20521101)
Two novel lanthanide-organic polymers [Er2(pdc)2(o-bdc)(H2O)2]·H2O(1,H2pdc = 2,6-pyridinedicarboxylic acid,o-H2bdc = 1,2-benzenedicarboxylic acid) and Er(Himdc)(mbdc)0.5(H2O)(2,H3imdc = 4,5-imidazoledi...
关键词:LANTHANIDE hydrothermal synthesis carboxylate-eontaining ligands 
Hydrothermal Synthesis and Structure of One New Polyoxotungsate [Ni(trien)]_4[Ni_4(H_2O)_2(HPW_9O_(34))_2]·4H_2O
《Chinese Journal of Structural Chemistry》2010年第1期74-80,共7页赵丹 郑寿添 杨国昱 
supported by the National Natural Science Fund for Distinguished Young Scholars of China (No 20725101);the 973 Program (No 2006CB932904);the NSF of Fujian Province (No E0510030);the NNSFC (No 20521101);the Research Foundation of Education Bureau of Fujian Province (No JA08053)
One new sandwich-type tetra-nickel substituted polyoxotungsate,[Ni(trien)]4-[Ni4(H2O)2(HPW9O34)2]·4H2O(1,trien=triethylenetetramine),has been hydrothermally synthesized and characterized by IR,elemental analy...
关键词:POLYOXOTUNGSTATE SUBSTITUTE transition metal crystal structure 
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