国家自然科学基金(Project29872010)

作品数：5被引量：0H指数：0
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相关作者：张永敏张纪明更多>>
相关机构：浙江大学更多>>
相关期刊：《合成化学》《Chinese Chemical Letters》《厦门大学学报（自然科学版）》更多>>
相关主题：SMREDUCTION金属钐叠氮化合物IH更多>>
相关领域：理学更多>>
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Sm/AlCl3·6H2O体系促进的叠氮化合物的化学选择性还原:一种制备胺的新方法
《合成化学》2002年第6期498-500,503,共4页张纪明 张永敏 
the National Natural Science Foundation of China(Project No.29872010);Natural Science Foundation of Zhejiang Province for financial support.
在金属钐和六水合三氯化铝的存在下 。
关键词：叠氮化合物 胺 金属钐 六水合三氯化铝 还原 
Reduction of Elemental Selenium by Samarium Diiodide: the Synthesis of Dithiodiselenides and Dithioselenides
《Chinese Chemical Letters》2001年第5期379-382,共4页Hong Yun GUO Yun Fa ZHENG Yong Min ZHANG 
We are grateful to the National Natural Science Foundation of China(Project No.29872010);NSF of Zhejiang Province,China for the financial support.
The reduction of elemental selenium by samarium diiodide led to selective formation of selenolate anion species (Se-2(2-) and Se2-), these nucleophilic species reacted readily with sodium alkyl thiosulfates to afford ...
关键词：SYNTHESIS samarium diiodide dithiodiselenides dithioselenides. 
A New Approach to 2,3-Dihydro-1H-1,5-Benzodiazepines from the Reaction of o-Nitrophenylazide with α,β-Unsaturated Ketones Promoted by Samarium Diiodide
《Chinese Chemical Letters》2001年第1期5-6,共2页Xiao Yuan CHEN Wei Hui ZHONG Yong Min ZHANG 
We thank the National Natural Science Foundation of China (Project No.29872010) ; NSF of Zhejiang province for financial support.
o-Nitrophenylazide was reduced by SmI2 in anhydrous THF at room temperature to produce active intermediate 2 (samarium amide), "living" double-anion in situ which reacted smoothly with α，β-unsaturated ketones to af...
关键词：Samarium diiodide reduction nitro group azide 2 3-dihydro-1H-1 5-benzodiazepine. 
Simultaneous Reduction of Nitro Group and S-S Bond in Nitrodisulfides by Samarium Diiodide: A New Approach to Benzothiazolines
《Chinese Chemical Letters》2000年第5期387-388,共2页Xiao Yuan CHEN Wei Hui ZHONG Yong Min ZHANGI (Department of Chemistry Zhejiang University at Xixi Campus. Hangzhou 310028 Department of Chemistry.Hunan Jishou University. Jishou 416000) 
We thank the National Natural Science Foundation of China (Project! No.29872010);the Laboratory of Organometallic Chemistry,
Nitrodisulfides were reduced by SmI2/HMPA in anhydrous THF at room temperature to produce active intermediates (samarium thiolates and amides), which were 'living' double-anions and reacted smoothly with aldehydes or ...
关键词：samarium diiodide REDUCTION nitro group DISULFIDE benzothiazoline 
A Novel Method for the Synthesis of Selenoesters and Unsymmetrical Aryl Selenides by Sm/cat. CoCl_3 System
《厦门大学学报（自然科学版）》1999年第S1期328-328,共1页陈仁尔 吴华悦 张永敏 
We thank the National Natural Science Foundation of China! (Project No. 29872010);he NSF of Zhejiang Province and the Laborat
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