Project supported by the National Natural Science Foundation of China, Chinese Academy of Sciences, the Major Basic Research Development Program of China (No. 2006CB806106), the Science and Technology Commission of Shanghai Municipality and Merck Research Laboratories.
We herein report on solution structural studies of Ru^Ⅱ catalysts (3a, 9) composed of achiral bisphosphine ligands (4, 8) and the enantiopure 1,2-diphenylethylenediamine (DPEN). Complete chiral induction from e...