supported by the National Natural Science Foundation of China(Nos.21233009,90922021,20773130,20733003,20803080,20973175);the“Knowledge Innovation Program of the Chinese Academy of Sciences”(KJCX2-YW-H20,CXJJ-11-M71)
In order to explain the opposite phase matchability of two types of newly discovered chalcogenides, AX2MQ6 vs AX4M5Q12 belonging to the same R3 space group, the linear and nonlinear optical properties are calculated. ...
Supported by the National Natural Science Foundation of China(90922021,20773130,20733003,20803080,20973175);"Knowledge Innovation Program of the Chinese Academy of Sciences"(KJCX2-YW-H20,CXJJ-11-M71)
A new quaternary rare-earth sulfide, Cs0.75(6)Er443(5)In3.32(6)S12 (1), is discovered by high temperature solid state reactions with a slight excess of CsCI flux. The structure is characterized by single-cryst...
supported by grants from the 973 Program (2007CB815301);the National Natural Science Foundation of China (21073192, 20733003 and 20871114);the Science Foundation of CAS (KJCX2-YW-H20);Fujian Province (2009HZ0006-1,2006L2005)
Two new transition-metal organic coordination polymers [M(mna)2](M = Cd(1),Zn(2);mna = 2-mercaptonicotinic anion) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray dif...
supported by the 973 Program (2007CB815301);the National Natural Science Foundation of China (21073192,20733003 and 20871114);the Science Foundation of CAS (KJCX2-YW-H20);Fujian Province (2009HZ0006-1,2006L2005)
A new tri-nuclear mixed metal thiolate complex [Ag(PPh3)2]2[Ni(edtO2)2] 1 has been synthesized and structurally characterized by single-crystal diffraction.The molecule has a crystallographic inversion centre occu...
supported by the National Natural Science Foundation of China (20733003,20871114 and 20801055);the Science Foundation of CAS (KJCX2-YW-M05 and KJCX2-YW-H20);of Fujian Province (2009HZ0006-1,2006L2005)
Solvothermal reaction of lanthanide(Ⅲ) salts with fluorescein (2-(6-hydroxy3-oxo-3H-xanthen-9-yl)benzoic acid) led to a series of new coordination polymers {[Ln(C 20 H 11 O 5)(C 20 H 10 O 5)(H 2 O)]·DMF}...
supported by the State Key Laboratory of Structural Chemistry (CAS,SZD08002-2);National Basic Research Program of China (973 Program,2007CB815306);the National Natural Science Foundation of China (20903096,20733003);Young Scientist’s Foundation of Fujian Province (2006F3163);Knowledge Innovation Program of the Chinese Academy of Sciences
Solvothermal reaction of [WS4]2-with CuCN and trithiocyanuric acid(L1) in orga-nic solvents gave rise to a new W/Cu/S polymer with a 2D anionic network,namely [Et4N]2[WS4Cu3(C3N3S3H1.5)2](1).The anionic layer of...
Supported by the State Key Laboratory of Structural Chemistry (CAS);the National Natural Science Foundation of China (20733003, 20801055 and 20673118);the Science Foundation of CAS (KJCX2-YW-M05);Fujian Province (2006J0014, 2006F3132 and 2007J0171)
Treatment of resorcin[4]arene tetracarboxylic acid 1 with triethylamine in the presence of Co(CH3COO)2·4H2O and 4,4 -bipyridine gave a co-crystallization 14-·4Et3NH+(C32H20O164-·4Et3NH+,Mr=1069.27) from ethan...
supported by the State Key Laboratory of Structural Chemistry, NNSFC (20733003);Chinese Academy of Sciences (KJCX2-YW-M05);973 Program (2007CB815301, 2006CB932900);the NSF of Fujian Province (2006L2005, 2006J0014)
The creation of a porous magnet is a long-sought academic goal since magnetism and porosity are hostile to one another. While long-range magnetic ordering needs spin carriers of short separation through short bridges,...
supported by CAS (SZD08002-2);973 Program (2007CB815306);the NNSFC (20733003 and 20673117);the Young Scientist’s Foundation of Fujian Province (2006F3136)
The self-assembly reactions of [MOS3]^2- (M = W, Mo) with CuS2COCH3 in DMF produced two novel dodecanuclear Mo(W)/Cu/S heterometallic clusters, [Et4N]4[{MOS3}3Cu6S2- (CuS2COCH3)3]·H2O (1: M = W; 2: M = Mo)....