国家自然科学基金(20733003)

作品数:12被引量:10H指数:2
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相关作者:陈玲章永凡黄一枝更多>>
相关机构:中国科学院福建物质结构研究所更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《中国基础科学》更多>>
相关主题:CRYSTAL_STRUCTURESSYNTHESESCUTRINUCLEARW更多>>
相关领域:理学更多>>
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The First-principles Study on the Optical Anisotropy of R3 Space Group Chalcogenides AX2MQ6
《Chinese Journal of Structural Chemistry》2017年第9期1552-1561,共10页余桔颂 林华 郑宇君 吴新涛 吴立明 
supported by the National Natural Science Foundation of China(Nos.21233009,90922021,20773130,20733003,20803080,20973175);the“Knowledge Innovation Program of the Chinese Academy of Sciences”(KJCX2-YW-H20,CXJJ-11-M71)
In order to explain the opposite phase matchability of two types of newly discovered chalcogenides, AX2MQ6 vs AX4M5Q12 belonging to the same R3 space group, the linear and nonlinear optical properties are calculated. ...
关键词:nonlinear optical property BIREFRINGENCE phase matchability CHALCOGENIDES 
Synthesis,Structure,and Property of a Three-dimensional Channel Quaternary Compound:Cs_(0.75(6))Er_(4.43(5))In_(3.32(6))S_(12)被引量:3
《Chinese Journal of Structural Chemistry》2013年第12期1873-1879,共7页WANG Peng LIN Hua 
Supported by the National Natural Science Foundation of China(90922021,20773130,20733003,20803080,20973175);"Knowledge Innovation Program of the Chinese Academy of Sciences"(KJCX2-YW-H20,CXJJ-11-M71)
A new quaternary rare-earth sulfide, Cs0.75(6)Er443(5)In3.32(6)S12 (1), is discovered by high temperature solid state reactions with a slight excess of CsCI flux. The structure is characterized by single-cryst...
关键词:high temperature solid state crystal structure magnetic property optical band gap 
Two New Coordination Polymers Assembled with a Functionalized Ligand:Syntheses and Crystal Structures被引量:3
《Chinese Journal of Structural Chemistry》2012年第1期115-121,共7页袁宁 盛天录 胡胜民 傅瑞标 吴新涛 
supported by grants from the 973 Program (2007CB815301);the National Natural Science Foundation of China (21073192, 20733003 and 20871114);the Science Foundation of CAS (KJCX2-YW-H20);Fujian Province (2009HZ0006-1,2006L2005)
Two new transition-metal organic coordination polymers [M(mna)2](M = Cd(1),Zn(2);mna = 2-mercaptonicotinic anion) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray dif...
关键词:zinc cadmium crystal structure 2-mercaptonicotinic acid hydrothermal reaction 
Synthesis and Crystal Structure of a Heterometallic Trinuclear Ni/Ag/S Compound
《Chinese Journal of Structural Chemistry》2012年第1期127-130,共4页靳美亮 马骁 谭春红 沈超君 朱启龙 胡胜民 傅瑞标 盛天录 吴新涛 
supported by the 973 Program (2007CB815301);the National Natural Science Foundation of China (21073192,20733003 and 20871114);the Science Foundation of CAS (KJCX2-YW-H20);Fujian Province (2009HZ0006-1,2006L2005)
A new tri-nuclear mixed metal thiolate complex [Ag(PPh3)2]2[Ni(edtO2)2] 1 has been synthesized and structurally characterized by single-crystal diffraction.The molecule has a crystallographic inversion centre occu...
关键词:heterometallic chalcogenides THIOLATE chair-like crystal structure 
Syntheses and Crystal Structures of a Series of Coordination Complexes Derived from the Fluorescein Ligand
《Chinese Journal of Structural Chemistry》2011年第2期230-234,共5页黄艺辉 盛天录 傅瑞标 胡胜民 沈超君 朱起龙 马骁 吴新涛 
supported by the National Natural Science Foundation of China (20733003,20871114 and 20801055);the Science Foundation of CAS (KJCX2-YW-M05 and KJCX2-YW-H20);of Fujian Province (2009HZ0006-1,2006L2005)
Solvothermal reaction of lanthanide(Ⅲ) salts with fluorescein (2-(6-hydroxy3-oxo-3H-xanthen-9-yl)benzoic acid) led to a series of new coordination polymers {[Ln(C 20 H 11 O 5)(C 20 H 10 O 5)(H 2 O)]·DMF}...
关键词:isomorphous LANTHANIDE FLUORESCEIN crystal structure 
多基团协同作用构建具有强倍频效应的硼酸盐非线性光学材料——Pb_2B_5O_9I
《中国基础科学》2011年第1期18-20,共3页黄一枝 章永凡 陈玲 
国家自然科学基金重点项目(20733003);国家自然科学基金重大研究计划培育项目(90922021)
本研究将具有孤对电子效应的Pb2+阳离子和弱电负性的I-阴离子同时引入五硼酸框架结构,构建出一种相匹配、强倍频效应的非线性光学晶体材料Pb2B5O9I。该材料在近紫外至中红外波段具有良好的透光性,其粉末倍频效应达到商用非线性光学基准...
关键词:非线性光学材料 倍频效应 硼酸盐 孤对电子效应 I-阴离子 
A New Layer W/Cu/S Polymer with Heterobimetallic Nodes and Tridentate Trithiocyanuric Acid被引量:1
《Chinese Journal of Structural Chemistry》2010年第12期1874-1878,共5页李志华 林建地 田崇斌 林平 杜少武 
supported by the State Key Laboratory of Structural Chemistry (CAS,SZD08002-2);National Basic Research Program of China (973 Program,2007CB815306);the National Natural Science Foundation of China (20903096,20733003);Young Scientist’s Foundation of Fujian Province (2006F3163);Knowledge Innovation Program of the Chinese Academy of Sciences
Solvothermal reaction of [WS4]2-with CuCN and trithiocyanuric acid(L1) in orga-nic solvents gave rise to a new W/Cu/S polymer with a 2D anionic network,namely [Et4N]2[WS4Cu3(C3N3S3H1.5)2](1).The anionic layer of...
关键词:W(Mo)/Cu/S polymer trithiocyanuric acid heterobimetallic nodes structure semiconductor 
Co-crystallization of Resorcin[4]arene Tetracarboxylic Acid with Triethylamine:Synthesis and Crystal Structure
《Chinese Journal of Structural Chemistry》2010年第1期114-120,共7页邹青竹 陈建珊 傅瑞标 胡胜民 盛天录 王欣 沈超君 陈东波 吴新涛 
Supported by the State Key Laboratory of Structural Chemistry (CAS);the National Natural Science Foundation of China (20733003, 20801055 and 20673118);the Science Foundation of CAS (KJCX2-YW-M05);Fujian Province (2006J0014, 2006F3132 and 2007J0171)
Treatment of resorcin[4]arene tetracarboxylic acid 1 with triethylamine in the presence of Co(CH3COO)2·4H2O and 4,4 -bipyridine gave a co-crystallization 14-·4Et3NH+(C32H20O164-·4Et3NH+,Mr=1069.27) from ethan...
关键词:RESORCINARENES crystal structure supramolecular chemistry carboxylic acid derivations 
Cluster-based Magnetic Porous Coordination Polymers被引量:2
《Chinese Journal of Structural Chemistry》2009年第11期1349-1358,共10页项生昌 王欣 胡胜民 盛天录 
supported by the State Key Laboratory of Structural Chemistry, NNSFC (20733003);Chinese Academy of Sciences (KJCX2-YW-M05);973 Program (2007CB815301, 2006CB932900);the NSF of Fujian Province (2006L2005, 2006J0014)
The creation of a porous magnet is a long-sought academic goal since magnetism and porosity are hostile to one another. While long-range magnetic ordering needs spin carriers of short separation through short bridges,...
关键词:MAGNETISM POROSITY coordination polymers CLUSTER amino acids CITRATE 
Syntheses and Characterization of Two Novel Mo(W)/Cu/S Dodecanuclear Clusters with Triple Incomplete Cubane-like Structure
《Chinese Journal of Structural Chemistry》2009年第11期1475-1479,共5页李建荣 林平 李志华 杜少武 
supported by CAS (SZD08002-2);973 Program (2007CB815306);the NNSFC (20733003 and 20673117);the Young Scientist’s Foundation of Fujian Province (2006F3136)
The self-assembly reactions of [MOS3]^2- (M = W, Mo) with CuS2COCH3 in DMF produced two novel dodecanuclear Mo(W)/Cu/S heterometallic clusters, [Et4N]4[{MOS3}3Cu6S2- (CuS2COCH3)3]·H2O (1: M = W; 2: M = Mo)....
关键词:thioltungstate thiomolybdate dececanuclear Mo(W)/Cu/S clusters crystal structure 
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