国家自然科学基金(20832003)

作品数：3被引量：1H指数：1
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相关期刊：《Science Bulletin》《Science China Chemistry》更多>>
相关主题：MEDIATEDINTRAMOLECULARINCL3FRIEDEL-CRAFTSANNULATION更多>>
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Mechanistic aspects of oxidation of palladium with O_2
《Science China Chemistry》2012年第10期2027-2035,共9页JIN LiQun LEI AiWen 
supported by the National Natural Science Foundation of China (21025206, 20832003, and 20972118);the National Basic Research Program of China, 973 Program (2012CB725302);Academic Award for Excellent Ph.D. Candidates Funded by Ministry of Education of China
Palladium-catalyzed aerobic transformation has been one of the most challenging topics within organometallics chemistry. Recently, the corresponding methodology has been developed rapidly, involving alcohol oxidation,...
关键词：PALLADIUM O2 MECHANISM 
InCl_3-mediated intramolecular Friedel-Crafts-type cyclization and its application to construct the [6-7-5-6] tetracyclic scaffold of liphagal被引量：1
《Science China Chemistry》2012年第1期36-42,共7页JIANG Hao TIAN LuFeng LI ZhenTao LIU Qi LI ChuangChuang YAO XinSheng YANG Zhen 
supported by the grants of National Basic Research Program(973 Program,2010CB833201 & 2009CB940904);the National Science and Technology Major Project "Development of Key Technology for the Combinatorial Synthesis of Privileged Scaffolds" (2009ZX09501-012);the National Natural Science Foundation of China(20821062,20832003 and 20902007)
A unified strategy toward the construction of the [5.7.6]tricyclic skeleton of liphagal is reported,featuring InCl3-mediated intramolecular Friedel-Crafts-type cyclization.
关键词：synthesis liphagal InCl3-mediated intramolecular Friedel-Crafts ANNULATION 
A novel self-promoted Morita-Baylis-Hillman-like dimerization
《Chinese Science Bulletin》2010年第25期2794-2798,共5页LI Qiang WongKhan Kittiya LUO XianCai Batsanov Andrei S Howard Judith A K LAN Yu WU YunDong Marder Todd B LEI AiWen 
supported by the National Natural Science Foundation of China (20832003,20772093)
While stable in CH2Cl2, hexane or THF, in the presence of MeOH, self-promoted dimerization of the triarylphosphine-alkene 1, a ligand for Pd-catalyzed reactions, produced an unusual racemic bis(phosphine) 2 in high yi...
关键词：二聚体 催化反应 二氯甲烷 四氢呋喃 氧化加成 DBA 芳基碘 烯烃 
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