supported by the National Natural Science Fund for Distinguished Young Scholars of China (No 20725101);the 973 Program (No 2006CB932904);the NSF of Fujian Province (Nos E0510030 and 2008F3120);the Knowledge Innovation Program of CAS (No KJCX2YWH01);the NNSFC (No 20521101)
Two novel lanthanide-organic polymers [Er2(pdc)2(o-bdc)(H2O)2]·H2O(1,H2pdc = 2,6-pyridinedicarboxylic acid,o-H2bdc = 1,2-benzenedicarboxylic acid) and Er(Himdc)(mbdc)0.5(H2O)(2,H3imdc = 4,5-imidazoledi...
supported by the National Natural Science Fund for Distinguished Young Scholars of China (No 20725101);the 973 Program (No 2006CB932904);the NSF of Fujian Province (No E0510030);the NNSFC (No 20521101);the Research Foundation of Education Bureau of Fujian Province (No JA08053)
One new sandwich-type tetra-nickel substituted polyoxotungsate,[Ni(trien)]4-[Ni4(H2O)2(HPW9O34)2]·4H2O(1,trien=triethylenetetramine),has been hydrothermally synthesized and characterized by IR,elemental analy...
supported by the National Natural Science Fund for Distinguished Young Scholars of China (No. 20725101);the 973 Program (No. 2006CB932904);the NSF of Fujian Province (Nos. E0510030 and 2008F3120);the Knowledge Innovation Program of CAS (No. KJCX2.YW.H01);NNSFC (No. 20521101)
A 3-D supramolecular framework, [Er(pybz)2(Hnds)(H2O)2]·H2O (1, Hpybz = 4- pyridin-4-yl-benzoic acid, H2nds = naphthalene-1,5-disulfonic acid), based on lanthanide ions and mixed ligands has been hydrothermal...
Supported by the NNSF for Distinguished Young Scholars of China (No. 20725101);the 973 program (No. 2006CB932900);the NNSFC (No. 20521101);the NSF of Fujian Province (No. E0510030);Key Project from CAS (No. KJCX2-YW-H01)
A novel hexa-NiⅡ substituted trilacunary Keggin polyoxometalate [{Ni6(μ3- OH)3(en)3(H2O)6}(B-α-PW9O34)]-6H2O 1 (en = ethylenediamine) has been hydrothermally synthesized and characterized by IR spectra, e...
Supported by 973 Program (2006CB932900);NNSFC (90206040, 20325106, 20521101);NSF of Fujian Province (2005HZ01-1, E0520003, 2005J058, 2006F3134);"The Distinguished Oversea Scholar Project" and "One Hundred Talent Project" from CAS
Four configurationally and conformationally related Zn(II) complexes with a tridentate ligand namely, N-(2-pyridylmethyl)-phenylalanine (Hpmpa), have been synthesized by hydrothermal reactions. [Zn(L-α-pmpa)2...
supported by the NNSFC (20521101);NSF for Distinguished Young Scientist of China (20425104);NSF of Fujian Province (2007J0173);the Fund of Fujian Key Laboratory of Nanomaterials (2006L2005)
Two new quaternary sulfides, KSmSiS4 (1) and KYbSiS4 (2), have been synthesized by high-temperature solid-state reaction. Single,crystal X-ray diffraction analyses indicate that both compounds crystallize in the s...
supported by 973 Program (2006CB932900);National Natural Science Foundation of China (No. 20571074 and 20521101)
The title compound, [Pd(2,2′-bipy)2](Haadip)2·4H2O, was synthesized via the hydrothermal reaction of PdCl2 with 5-aminodiacetic isophthalic acid (H4adip) in an acetic acid water solution. It was characterized ...
National Natural Science Foundation of China (Nos. 20573113 and 20521101); NSF of Fujian Province (No. E0420003)
A new polar intermetallic compound, Eu3Sn5, has been synthesized by solid-state reaction of the corresponding pure elements in a stoicbiometric ratio in a welded tantalum tube at high temperature. Its crystal structur...
the NNSFC (20571075, 20521101);the NSF for Distinguished Young Scientist of China (20425104);the NSF of Fujian Province (E0510028)
ABSTRACT A new lanthanumm-ironm complex [La(DMSO)5(H2O)](μ-CN)2[Fe(CN)4]·H2O 1 (DMSO = dimethylsulfoxide) has been prepared by a facile approach, ball-milling method, and characterized by X-ray diffraction...
The project was supported by the NNSFC (20571075, 20521101);the NSF for Distinguished Young Scientists of China (20425104) ;the NSF of Fujian Province (A0420002)
The solvothermal reaction of 3-amino-1H-1,2,4-triazole (ttr) with Zn(ClO4)2·6H2O and NaCl in a 1:1:1 molar ratio gave a new complex [Zn(ttr)Cl]n with a 3-connected (4.82) 2-D structure. The layers stack in ...