国家重点基础研究发展计划(2009CB421606)

作品数:11被引量:18H指数:3
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相关作者:卫皇曌何松波孙承林陈吉平倪余文更多>>
相关机构:中国科学院中国科学院研究生院西安建筑科技大学中国科学院生态环境研究中心更多>>
相关期刊:《Baosteel Technical Research》《工业催化》《Science China Chemistry》《环境化学》更多>>
相关主题:加氢脱氯催化湿式氧化COMPOSITE飞灰AU更多>>
相关领域:理学环境科学与工程化学工程一般工业技术更多>>
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金属氧化物对十氯联苯的降解研究被引量:8
《中国科学:化学》2014年第10期1665-1674,共10页刘莎 石瑞芳 黄学敏 黄林艳 刘烨煊 黎烈武 芦会杰 杨帆 苏贵金 
中国科学院知识创新工程重要方向项目(KZCX2-YW-QN407);国家高技术研究发展计划(2012AA062803);国家重点基础研究发展计划(2009CB421606);国家自然科学基金项目(21177141,51078346)
分别以市售的Fe2O3、MgO和CaO为催化剂,对十氯联苯(CB209)进行了催化降解研究.结果表明,MgO对CB209的降解具有较高的活性.在反应温度为300℃,反应时间为60 min时,MgO对CB209的降解效率达到98.9%.进一步研究表明,MgO催化降解CB209的动力...
关键词:金属氧化物 十氯联苯 加氢脱氯 氧化反应 碳碳桥键 
In-situ STM observation of the phase transition of two-dimensional 2,5-distyrylpyrazine nanostructure adsorbed on Au(111) in an electrochemical environment
《Science China Chemistry》2013年第5期672-677,共6页SU GuiJin HUANG LinYan ZHANG LiXia LU HuiJie 
supported by the Chinese Academy of Sciences (KZCX2-YW-QN407);the National 973 Program (2009CB421606);the National Natural Science Foundation of China (51078346, 21177141);Youth Innovation Promotion Association, CAS;the Project sponsored by SRF for ROCS, SEM
The phase transition of 2,5-distyrylpyrazine (DSP) adsorbed on Au(111) substrate was studied as a function of the substrate potential in 0.1 M HC104, using an in situ scanning tunneling microscope (STM). Dependi...
关键词:2 5-distyrylpyrazine Au(111) scanning tunneling microscopy phase transition 
催化湿式氧化法和厌氧发酵法联用处理异佛尔酮废水被引量:1
《工业催化》2012年第11期69-75,共7页闫晓淼 卫皇曌 杨旭 何松波 李敬美 孙承林 
国家高技术研究发展计划(863计划)项目(2009AA063903);国家重点基础研究发展计划(973计划)项目(2009CB421606)
分别以沉淀法、共沸蒸馏法和高温老化法制备ZrO2载体,采用等体积浸渍法制备Ru/ZrO2催化剂,用于催化湿式氧化法处理异佛尔酮废水。研究了反应温度、催化剂用量及反应时间对异佛尔酮废水乙酸浓度、COD去除率、TOC去除率及废水可生化性的...
关键词:催化化学 催化湿式氧化 异佛尔酮 Ru ZRO2 厌氧发酵 乙酸 甲烷 
Preparation,characterization and catalytic behavior of hierachically porous CuO/α-Fe_2O_3/SiO_2 composite material for CO and o-DCB oxidation
《Journal of Natural Gas Chemistry》2011年第6期618-622,共5页Xiaodong Ma Xi Feng Xuan He Hongwen Guo Lu Lu 
supported by the National Natural Science Foundation of China (No. 20977052 and 21177066);the Science and Technology Commission Foundation of Tianjin (No. 11JCYBJC05100);the Chinese Academy of Sciences(No. KZCX2-YW-420);the National 973 program (No. 2009CB421606)
Hierachically porous (HP) CuO/α-Fe2O3/SiO2 composite material was fabricated by sol-gel method and multi-hydrothermal processes using HP-SiO2 as support.The resulting material was characterized by N2 adsorption-des...
关键词:CO and o-DCB oxidation hierachically porous CuO/α-Fe2O3/HP-SiO2 monolith 
Gas-particle partitioning of polychlorinated dibenzo-p-dioxins and dibenzofurans in the sintering process
《Baosteel Technical Research》2011年第3期59-64,共6页YU Yongmei HE Xiaolei LI Xianwei 
supported by the National Natural Science Foundation of China(21037003,20921063);the National 973 Program(2009CB421606)
The distribution of seventeen gaseous and particle-bound 2,3,7,8-substituted chlorinated PCDD/Fs in the flue gas of different windboxes of the sintering machine was analyzed. The influence of temperature change on the...
关键词:DIOXINS SINTERING formation mechanism 
五氯酚催化湿式氧化降解反应及动力学研究被引量:3
《环境化学》2011年第7期1297-1302,共6页卫皇曌 何松波 乔瑞平 孙承林 陈东 李悦 
国家973基金(2009CB421606);十一五国家863计划(2009AA063903);中国科学院知识创新工程领域前沿项目(K2009D02);所青年基金-博士科研探索课题(S2010144)资助
以高温老化法制备了ZrO2载体,其比表面积为251.6 m.2g-1,采用等体积浸渍法制备了Ru/ZrO2催化剂,用于催化湿式氧化法处理五氯酚.研究了反应温度、氧气分压、PCP初始浓度及时间对PCP转化率的影响.研究结果表明,提高反应温度、增加氧气分...
关键词:催化湿式氧化 五氯酚 动力学 Ru/ZrO2 
醇胺类物质促进飞灰中氯代芳烃加氢脱氯的研究
《环境化学》2011年第2期405-411,共7页朱美文 倪余文 樊芸 陈吉平 
国家重点基础研究计划(2009CB421606);国家自然科学基金(20977091);国家科技支撑计划(2008BAC32B03)资助项目
分别以三乙醇胺(TEA)和一乙醇胺(MEA)作为氢源,六氯苯(HCB)作为模型化合物,研究了在密闭体系下飞灰中氯代芳烃的加氢脱氯作用.考察了TEA或MEA添加量、热处理温度和时间对脱氯效率的影响,证实有明显的脱氯反应发生.当MEA或TEA添加量为8%...
关键词:飞灰 醇胺 加氢脱氯 六氯苯 
Hierarchically porous Fe_2O_3 /CuO composite monoliths:Synthesis and characterization
《Journal of Natural Gas Chemistry》2010年第6期589-592,共4页Xiaodong Ma Hongwen Sun Quan Sun Hongwen Guo Bo Fan Shuo Zhao 
supported by the National Natural Science Foundation of China(No. 20977052);the Chinese Academy of Sciences(Grant No. KZCX2-YW-420);the National 973 Program(No. 2009CB421606)
In this paper,hierarchically porous Fe2O3 /CuO composite monoliths were first successfully synthesized by a mild method using silica monoliths as templates.The structure of composite monoliths was characterized by X-r...
关键词:hierarchically porous Fe2O3/CuO composite monolith synthesis characterization 
ECSTM study of adsorption of C_(60),C_(70),C_(86) and Y@C_(82) on Au(111)被引量:1
《Science China Chemistry》2010年第8期1705-1710,共6页SU GuiJin1,JIA ManKe1,GAN LiHua2 & SHI RuiFang1 1State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China 2School of Chemistry and Chemical Engineering,Southwest University,Chongqing 400715,China 
support from the Chinese Academy of Sciences (KZCX2-YW-QN407);the National Natural Science Foundation of China (20807049);the National Basic Research Program of China (2009CB421606);the Project-sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Ministry of Education
The adsorption of a variety of fullerenes (C60,C70,C86,Y@C82) on Au(111) electrode surfaces was comprehensively investigated in 0.1 M HClO4 by electrochemical scanning tunneling microscopy (ECSTM).In the ordered C60's...
关键词:C60 C70 C86 Y@C82 ECSTM Au(111) 
Synthesis of a magnetic micro/nano Fe_xO_y-CeO_2 composite and its application for degradation of hexachlorobenzene被引量:4
《Science China Chemistry》2010年第6期1266-1272,共7页JIA ManKe,SU GuiJin,ZHENG MingHui,ZHANG Bing & LIN ShiJing State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China 
the support from the Chinese Academy of Sciences (KZCX2-YW-420 & KZCX2-YW-QN407);the National Basic Research Program of China (2009CB421606);the National Natural Science Foundation of China (20921063 & 20807049);the Project sponsored by Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education
A micrometer-sized nanostructured,magnetic,ball-like FexOy-CeO2 composite was synthesized through an ethylene-glycol mediated process.The synthesized samples were characterized by scanning electron microscopy combined...
关键词:FexOy-CeO2 COMPOSITE 3D micro/nanostructures DEGRADATION of HEXACHLOROBENZENE 
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