国家自然科学基金(20803058)

作品数:26被引量:56H指数:5
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相关作者:宋纪蓉赵凤起徐抗震任莹辉马海霞更多>>
相关机构:西北大学西安近代化学研究所故宫博物院河南科技学院更多>>
相关期刊:《无机化学学报》《含能材料》《Chinese Journal of Structural Chemistry》《固体火箭技术》更多>>
相关主题:晶体结构FOX-7热行为1,1-二氨基-2,2-二硝基乙烯比热容更多>>
相关领域:理学化学工程兵器科学与技术航空宇航科学技术更多>>
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AEFOX-7的晶体结构和燃烧焓(英文)被引量:2
《含能材料》2015年第12期1235-1239,共5页孙倩 李彦峰 徐抗震 宋纪蓉 赵凤起 
National Natural Science Foundation of China(21241003 and 20803058);Postdoctoral Science Foundation of Shaanxi Province and Education Committee Foundation of Shaanxi Province(2013JK0697)
制备了1-氨基-1-乙氨基-2,2-二硝基乙烯(AEFOX-7)水合物的单晶并测定了其结构,该晶体属于立方晶系,空间群是Pna2(1)/m,晶体参数为:a=1.3692(3)nm,b=0.71240(16)nm,c=0.9024(2)nm,β=90°,V=0.8802(4)nm^3,Z=4,μ=0.133 mm^(-1),F(000)=4...
关键词:1 1-二氨基-2 2-二硝基乙烯(FOX-7) 1-氨基-1-乙氨基-2 2-二硝基乙烯(AEFOX-7) 晶体结构 燃烧焓 
Non-isothermal Decomposition Kinetics of [Cu(en)2H2O] (FOX-7)2·H2O
《Chemical Research in Chinese Universities》2014年第4期672-675,共4页ZHANG Yu DONG Kaiyue QIU Qianqian XU Kangzhen HE Fei SONG Jirong ZHAO Fengqi 
Supported by the National Natural Science Foundation of China(Nos. 21241003, 20803058), the Science and Technology Research and Development Program of Shaanxi Province, China(No.2013K02-25) and the Education Committee Foundation of Shaanxi Province, China(No.2013JK0697).
The thermal behavior and non-isothermal decomposition kinetics of [Cu(en)2H2O](FOX-7)2·H2O (en=ethylenediamine) were studied with DSC and TG-DTG methods.The kinetic equation of the exothermal process is dα/dt=...
关键词:1 1-Diamino-2 2-dinitroethylene(FOX-7) Copper complex Non-isothermal decomposition kinetics Thermal property 
[Zn(en)_3](FOX-7)_2的合成、晶体结构和热行为(英文)被引量:1
《含能材料》2014年第4期436-440,共5页袁志锋 张钰 高哲 徐抗震 宋纪蓉 赵凤起 
National Natural Science Foundation of China(21241003 and 20803058);Education Committee Foundation of Shaanxi Province(2013JK0697)
合成了一种新型含能锌配合物[Zn(en)3](FOX-7)2,并测定其晶体结构。该晶体属单斜晶系,空间群C2/c,晶胞参数为:a=0.77170(16)nm,b=1.6720(3)nm,c=1.6996(3)nm,β=94.333(3)°,V=2.1867(7)nm3,Z=4,μ=1.194mm-1,F(000)=1112,Dc=1.628g·cm...
关键词:结构化学 1 1-二氨基-2 2-二硝基乙烯(FOX-7) 锌化合物 晶体结构 热行为 
Cu(NH_3)_2(FOX-7)_2的非等温分解动力学(英文)被引量:1
《含能材料》2014年第2期206-209,共4页邱欠欠 高哲 陈咏顺 徐抗震 赵凤起 
the National Natural Science Foundation of China(21241003 and 20803058);Education Committee Foundation of Shaanxi Province(2013JK0697)
利用DSC和TG-DTG法研究了Cu(NH3)2(FOX-7)2的热分解行为。第一放热分解过程的非等温分解动力学方程为dα=dT1015.124α3/4exp(-1.429×105/RT)。Cu(NH.5℃和156.2℃。利用β3)2(FOX-7)2的自加速分解温度和热爆炸临界温度分别为145微量...
关键词:物理化学 1 1-氨基-2 2-硝基乙烯(FOX-7) 铜配合物 非等分解温动力学 
Non-isothermal Decomposition Kinetics of K(AHDNE)
《Chemical Research in Chinese Universities》2012年第5期878-881,共4页LU Lei XU Kang-zhen QIU Qian-qian WANG Gang SONG Ji-rong ZHAO Feng-qi 
Supported by the National Natural Science Foundation of China(No.20803058);the Shaanxi Provincial Science Program Foundation, China(No.2011kjxx31);the Education Committee Foundation of Shaanxi Province, China(Nos.2010JK881,12JK0636)
The thermal behavior and non-isothermal decomposition kinetics of 1-amino-1-hydrazino-2,2-dinitro-ethylene potassium salt[K(AHDNE)] were studied under the non-isothermal conditions by different scanning calorimeter...
关键词:1-Amino-1-hydrazino-2 2-dinitroethylene(AHDNE) Potassium salt Non-isothermal decomposition kine- tics 
Synthesis,Crystal Structure and Thermal Behavior of 4,5-Dimethoxy-2-(dinitromethylene)imidazolidine
《Chemical Research in Chinese Universities》2012年第4期716-720,共5页WANG Min XU Kang-zhen HE Fei ZHANG Hang CHEN Yong-shun SONG Ji-rong ZHAO Feng-qi 
Supported by the National Natural Science Foundation of China(No.20803058);the Basal Science Foundation of National Defense(No.B0920110005);the Science Program Foundation of Shaanxi Province,China(No.2011kjxx31);the Education Committee Foundation of Shaanxi Province,China(No.2010JK881)
A new energetic material,4,5-dimethoxy-2-(dinitromethylene)imidazolidine(DMDNI),was synthesized by the reaction of 4,5-dihydroxyl-2-(dinitromethylene)-imidazolidine(DDNI) and methanol,and structurally characte...
关键词:Crystal structure Thermal behavior 4 5-Dimethoxy-2-(dinitromethylene)imidazolidine(DMDNI) 1 1-Diamino-2 2-dinitroethylene(FOX-7) 
FOX-7的反应性研究进展被引量:6
《含能材料》2012年第1期120-125,共6页陈咏顺 徐抗震 王敏 黄洁 马海霞 宋纪蓉 赵凤起 
国家自然科学基金(20803058);陕西省教育厅科技专项基金(2010JK881);火炸药国防重点实验室基金(9140C3503010905)资助
基于新型含能材料1,1-二氨基-2,2-二硝基乙烯(FOX-7)特殊的"推-拉"硝基烯胺结构,总结了FOX-7所能发生的化学反应,包括酸碱反应、配位反应、亲核取代、酰基化反应、氧化反应、还原反应、水解反应、氨基的亲电加成反应、叠氮反应等,从而...
关键词:应用化学 1 1-二氨基-2 2-二硝基乙烯(FOX-7) 硝基烯胺 有机合成 合成机理 
Cs(DNDZ)的合成、晶体结构和热行为研究(英文)被引量:2
《无机化学学报》2011年第11期2257-2262,共6页徐抗震 左现刚 张航 王敏 宋纪蓉 赵凤起 
国家自然科学基金(No.20803058);陕西省科技计划(No.2011kjxx31);陕西省教育厅科技专项基金(No.2010JK881)资助项目
合成了一种新型高能有机铯盐2-(二硝基亚甲基)-1,3-二氮杂环戊烷铯盐[Cs(DNDZ)],并培养出单晶。该晶体属单斜晶系,空间群P21/c,晶胞参数为:a=0.933 6(2)nm,b=0.677 42(14)nm,c=1.387 4(3)nm,β=101.173(2)°,V=0.860 8(3)nm3,Z=4,μ=4.2...
关键词:1 1-二氨基-2 2-二硝基乙烯(FOX-7) 2-(二硝基亚甲基)-1 3-二氮杂环戊烷(DNDZ) 晶体结构 热行为 
Synthesis, Crystal Structure and Thermal Behavior of 4,5-Diacetoxyl-2-(dinitromethylene)-imidazolidine被引量:1
《Chinese Journal of Chemistry》2011年第11期2293-2300,共8页徐抗震 王敏 张航 严彪 宋纪蓉 王伯周 赵凤起 
Project supported by the National Natural Science Foundation of China (No. 20803058), Basal Science Foundation of National Defense (No. B0920110005) and the Education Committee Foundation of Shaanxi Province (No. 2010JK881).
A new energetic material, 4,5-diacetoxyl-2-(dinitromethylene)-imidazolidine (DADNI), was synthesized by the reaction of 4,5-dihydroxyl-2-(dinitromethylene)-imidazolidine (DDNI) and acetic anhydride, and charac...
关键词:crystal structure thermal behavior 4 5-diacetoxyl-2-(dinitromethylene)-imidazolidine (DADNI) 1 1-diamino-2 2-dinitroethylene (FOX-7) acetic anhydride 
Thermal Behaviors of 2-(Dinitromethylene)-1,3- diazacycloheptane (DNDH)被引量:1
《Chinese Journal of Chemistry》2011年第8期1576-1582,共7页吕磊 徐抗震 王刚 罗金安 宋纪蓉 王伯周 赵凤起 
Project supported by the National Natural Science Foundation of China (No. 20803058), the Basal Science Foundation of National Defense (No. B 0920110005 ) and the Education Committee Foundation of S haanxi Province (Nos. 2010J K881, 09J K820).
2-(Dinitromethylene)-1,3-diazacycloheptane (DNDH) was prepared by the reaction of 1,1-diamino-2,2-dinitro- ethylene (FOX-7) with 1,4-diaminoethane in NMP. Thermal decomposition behavior of DNDH was studied under...
关键词:2-(dinitromethylene)-l 3-diazacycloheptane (DNDH) l l-diamino-2 2-dinitroethylene (FOX-7) ther-mal behavior nitrogen heterocycles THERMOCHEMISTRY 
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